Synthesis and electronic structure determination of N-alkyl-substituted bis(imino)pyridine iron imides exhibiting spin crossover behavior

Journal of the American Chemical Society

Volumn 133, Issue 43, 2011, Pages 17353-17369

  Bowman, Amanda C ^a,b   Milsmann, Carsten ^a,b,c   Bill, Eckhard ^b   Turner, Zoë R ^c   Lobkovsky, Emil ^a   Debeer, Serena ^a,b   Wieghardt, Karl ^b   Chirik, Paul J ^a,c  

^a Department of Obstetrics Gynecology   (United States)

^b MAX PLANCK INSTITUTE FOR CHEMICAL ENERGY CONVERSION   (Germany)

^c PRINCETON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ANTIFERRO-MAGNETICALLY COUPLED; CLOSED SHELLS; COMPUTATIONAL STUDIES; CRYOGENIC TEMPERATURES; DINITROGEN; EXPERIMENTAL DATA; FERRIC IONS; HIGHER TEMPERATURES; INTERMEDIATE SPINS; ISOMER SHIFTS; MOSSBAUER; PLANAR COMPOUNDS; REDOX-ACTIVE; SPECTROSCOPIC MEASUREMENTS; SPIN CROSSOVERS; SPIN TRANSITION; SQUID MAGNETIC MEASUREMENTS; SSBAUER SPECTROSCOPIES; STRUCTURE DETERMINATION; TEMPERATURE RANGE; THERMODYNAMIC PARAMETER; TWO-ELECTRON REDUCTION;

ABSORPTION SPECTROSCOPY; AMINES; CHELATION; DENSITY FUNCTIONAL THEORY; ELECTRONIC PROPERTIES; ELECTRONIC STRUCTURE; IRON; IRON COMPOUNDS; ORGANIC POLYMERS; PYRIDINE; TEMPERATURE; THERMOELECTRICITY; WETLANDS; X RAY DIFFRACTION;

SYNTHESIS (CHEMICAL);

IMIDE; IRON; N ALKYL SUBSTITUTED BIS(IMINO)PYRIDINE IRON IMIDE DERIVATIVE; PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; ELECTRONIC STRUCTURE; MOSSBAUER SPECTROSCOPY; SYNTHESIS; X RAY DIFFRACTION;

CRYSTALLOGRAPHY, X-RAY; ELECTRONS; FERRIC COMPOUNDS; FERROUS COMPOUNDS; IMIDES; MODELS, MOLECULAR; MOLECULAR STRUCTURE; PYRIDINES; STEREOISOMERISM;

EID: 80054980149     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja205736m     Document Type: Article

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