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Volumn 130, Issue 9, 2008, Pages 2716-2717

Thermodynamics of hydrogen atom transfer to a high-valent iron imido complex

Author keywords

[No Author keywords available]

Indexed keywords

IMIDE; IRON COMPLEX;

EID: 40949085628     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0776834     Document Type: Article
Times cited : (172)

References (34)
  • 5
    • 0347717615 scopus 로고    scopus 로고
    • Hydroxylation of C-H bonds up to 99 kcal/mol has been reported: Kaizer, J.; Klinker, E. J.; Oh, N. Y.; Rohde, J.-U.; Song, W. J.; Stubna, A.; Kim, J.; Münck, E.; Nam, W.; Que, L., Jr. J. Am. Chem. Soc. 2004, 126, 472.
    • Hydroxylation of C-H bonds up to 99 kcal/mol has been reported: Kaizer, J.; Klinker, E. J.; Oh, N. Y.; Rohde, J.-U.; Song, W. J.; Stubna, A.; Kim, J.; Münck, E.; Nam, W.; Que, L., Jr. J. Am. Chem. Soc. 2004, 126, 472.
  • 6
    • 0034623521 scopus 로고    scopus 로고
    • Structurally characterized iron(IV) imidos: (a) Verma, A. K.; Nazif, T. N.; Achim, C.; Lee, S. C. J. Am. Chem. Soc. 2000, 122, 11013.
    • Structurally characterized iron(IV) imidos: (a) Verma, A. K.; Nazif, T. N.; Achim, C.; Lee, S. C. J. Am. Chem. Soc. 2000, 122, 11013.
  • 9
    • 3242779327 scopus 로고    scopus 로고
    • HAT to transient iron(III) and iron(IV) imidos: (a) Avenier, F.; Latour, J.-M. Chem. Commun. 2004, 1544.
    • HAT to transient iron(III) and iron(IV) imidos: (a) Avenier, F.; Latour, J.-M. Chem. Commun. 2004, 1544.
  • 15
    • 0003096518 scopus 로고    scopus 로고
    • Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates
    • Meunier, B, Ed, Imperial College Press: London
    • Mayer, J. M. Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates. In Biomimetic Oxidations Catalyzed by Transition Metal Complexes; Meunier, B., Ed.; Imperial College Press: London, 2000; pp 1-43.
    • (2000) Biomimetic Oxidations Catalyzed by Transition Metal Complexes , pp. 1-43
    • Mayer, J.M.1
  • 22
    • 34548275022 scopus 로고    scopus 로고
    • For a detailed description of the bonding in pseudotetrahedral iron imido complexes see
    • For a detailed description of the bonding in pseudotetrahedral iron imido complexes see: Tangen, E.; Conradie, J.; Ghosh, A. J. Chem. Theory Comput. 2007, 3, 448.
    • (2007) J. Chem. Theory Comput , vol.3 , pp. 448
    • Tangen, E.1    Conradie, J.2    Ghosh, A.3
  • 24
    • 40949117370 scopus 로고    scopus 로고
    • In THF, E1/2, 0.64 V. For the related bis(phosphino)pyrazolylborate complex [PhBPtBu 2(pz)Fe≡NAd]B(3,5-(CF3)2C 6H3)4, E1/2, 0.72 V in THF. See ref 3b
    • 1/2 = -0.72 V in THF. See ref 3b.
  • 29
    • 33645506119 scopus 로고    scopus 로고
    • a's of these weak acids in MeCN have been extrapolated from the experimentally determined values in DMSO. See Kütt, A.; Leito, I.; Kaljurand, I.; Sooväli, L.; Vlasov, V. M.; Yagupolskii, L. M.; Koppel, I. A. J. Org. Chem. 2006, 71, 2829.
    • a's of these weak acids in MeCN have been extrapolated from the experimentally determined values in DMSO. See Kütt, A.; Leito, I.; Kaljurand, I.; Sooväli, L.; Vlasov, V. M.; Yagupolskii, L. M.; Koppel, I. A. J. Org. Chem. 2006, 71, 2829.
  • 30
    • 40949153209 scopus 로고    scopus 로고
    • a's of the weak acids. See SI for details.
    • a's of the weak acids. See SI for details.
  • 31
    • 40949128480 scopus 로고    scopus 로고
    • 1/2 + 59.5 in MeCN. Parker, V. D.; Handoo, K. L.; Roness, F.; Tilset M. J. Am. Chem. Soc. 1991, 113, 7493.
    • 1/2 + 59.5 in MeCN. Parker, V. D.; Handoo, K. L.; Roness, F.; Tilset M. J. Am. Chem. Soc. 1991, 113, 7493.
  • 33
    • 40949089873 scopus 로고    scopus 로고
    • Anthracene and 1-adamantylamine (51 ± 9% yield) were determined by GC/FID. See SI for details.
    • Anthracene and 1-adamantylamine (51 ± 9% yield) were determined by GC/FID. See SI for details.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.