-
1
-
-
0000208617
-
-
Recent reviews: a
-
Recent reviews: (a) Solomon, E. I.; Brunold, T. C.; Davis, M. I.; Kemsley, J. N.; Lee, S.-K.; Lehnert, N.; Neese, F.; Skulan, A. J.; Yang, Y.-S.; Zhou, J. Chem. Rev. 2000, 100, 235.
-
(2000)
Chem. Rev
, vol.100
, pp. 235
-
-
Solomon, E.I.1
Brunold, T.C.2
Davis, M.I.3
Kemsley, J.N.4
Lee, S.-K.5
Lehnert, N.6
Neese, F.7
Skulan, A.J.8
Yang, Y.-S.9
Zhou, J.10
-
2
-
-
1542378704
-
-
(b) Costas, M.; Mehn, M. P.; Jensen, M. P.; Que, L., Jr. Chem. Rev. 2004, 104, 939.
-
(2004)
Chem. Rev
, vol.104
, pp. 939
-
-
Costas, M.1
Mehn, M.P.2
Jensen, M.P.3
Que Jr., L.4
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5
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0347717615
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Hydroxylation of C-H bonds up to 99 kcal/mol has been reported: Kaizer, J.; Klinker, E. J.; Oh, N. Y.; Rohde, J.-U.; Song, W. J.; Stubna, A.; Kim, J.; Münck, E.; Nam, W.; Que, L., Jr. J. Am. Chem. Soc. 2004, 126, 472.
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Hydroxylation of C-H bonds up to 99 kcal/mol has been reported: Kaizer, J.; Klinker, E. J.; Oh, N. Y.; Rohde, J.-U.; Song, W. J.; Stubna, A.; Kim, J.; Münck, E.; Nam, W.; Que, L., Jr. J. Am. Chem. Soc. 2004, 126, 472.
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6
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0034623521
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Structurally characterized iron(IV) imidos: (a) Verma, A. K.; Nazif, T. N.; Achim, C.; Lee, S. C. J. Am. Chem. Soc. 2000, 122, 11013.
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Structurally characterized iron(IV) imidos: (a) Verma, A. K.; Nazif, T. N.; Achim, C.; Lee, S. C. J. Am. Chem. Soc. 2000, 122, 11013.
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-
-
7
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-
33646156655
-
-
(b) Thomas, C. M.; Mankad, N. P.; Peters, J. C. J. Am. Chem. Soc. 2006, 128, 4956.
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 4956
-
-
Thomas, C.M.1
Mankad, N.P.2
Peters, J.C.3
-
8
-
-
33751246489
-
-
Jr
-
(c) Klinker, E. J.; Jackson, T. A.; Jensen, M. P.; Stubna, A.; Juhász, G.; Bominaar, E. L.; Münck, E. Que, L., Jr. Angew. Chem., Int. Ed. 2006, 45, 7394.
-
(2006)
Angew. Chem., Int. Ed
, vol.45
, pp. 7394
-
-
Klinker, E.J.1
Jackson, T.A.2
Jensen, M.P.3
Stubna, A.4
Juhász, G.5
Bominaar, E.L.6
Münck, E.7
Que, L.8
-
9
-
-
3242779327
-
-
HAT to transient iron(III) and iron(IV) imidos: (a) Avenier, F.; Latour, J.-M. Chem. Commun. 2004, 1544.
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HAT to transient iron(III) and iron(IV) imidos: (a) Avenier, F.; Latour, J.-M. Chem. Commun. 2004, 1544.
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-
-
10
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23944521800
-
-
(b) Lucas, R. L.; Powell, D. R.; Borovik, A. S. J. Am. Chem. Soc. 2005, 127, 11596.
-
(2005)
J. Am. Chem. Soc
, vol.127
, pp. 11596
-
-
Lucas, R.L.1
Powell, D.R.2
Borovik, A.S.3
-
11
-
-
33750467367
-
-
(c) Eckert, N. A.; Vaddadi, S.; Stoian, S.; Lachicotte, R. J.; Cundari, T. R.; Holland, P. L. Angew. Chem., Int. Ed. 2006, 45, 6868.
-
(2006)
Angew. Chem., Int. Ed
, vol.45
, pp. 6868
-
-
Eckert, N.A.1
Vaddadi, S.2
Stoian, S.3
Lachicotte, R.J.4
Cundari, T.R.5
Holland, P.L.6
-
13
-
-
33646439286
-
-
(b) Bart, S. C.; Lobkovsky, E.; Bill, E.; Chirik, P. J. J. Am. Chem. Soc. 2006, 128, 5302.
-
(2006)
J. Am. Chem. Soc
, vol.128
, pp. 5302
-
-
Bart, S.C.1
Lobkovsky, E.2
Bill, E.3
Chirik, P.J.4
-
14
-
-
0141645556
-
-
Jensen, M. P.; Mehn, M. P.; Que, L., Jr.; Angew. Chem., Int. Ed. 2003, 42, 4357.
-
(2003)
Angew. Chem., Int. Ed
, vol.42
, pp. 4357
-
-
Jensen, M.P.1
Mehn, M.P.2
Que Jr., L.3
-
15
-
-
0003096518
-
Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates
-
Meunier, B, Ed, Imperial College Press: London
-
Mayer, J. M. Biomimetic Oxygenations Related to Cytochrome P450: Metal-Oxo and Metal-Peroxo Intermediates. In Biomimetic Oxidations Catalyzed by Transition Metal Complexes; Meunier, B., Ed.; Imperial College Press: London, 2000; pp 1-43.
-
(2000)
Biomimetic Oxidations Catalyzed by Transition Metal Complexes
, pp. 1-43
-
-
Mayer, J.M.1
-
16
-
-
2942679678
-
-
Green, M. T.; Dawson, J. H.; Gray, H. B. Science 2004, 304, 1653.
-
(2004)
Science
, vol.304
, pp. 1653
-
-
Green, M.T.1
Dawson, J.H.2
Gray, H.B.3
-
18
-
-
0037437343
-
-
(a) Brown, S. D.; Betley, T. A.; Peters, J. C. J. Am. Chem. Soc. 2003, 125, 322.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 322
-
-
Brown, S.D.1
Betley, T.A.2
Peters, J.C.3
-
21
-
-
33748788785
-
-
(d) Mehn, M. P.; Brown, S. D.; Jenkins, D. M.; Peters, J. C.; Que, L., Jr. Inorg. Chem. 2006, 45, 7417.
-
(2006)
Inorg. Chem
, vol.45
, pp. 7417
-
-
Mehn, M.P.1
Brown, S.D.2
Jenkins, D.M.3
Peters, J.C.4
Que Jr., L.5
-
22
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-
34548275022
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-
For a detailed description of the bonding in pseudotetrahedral iron imido complexes see
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For a detailed description of the bonding in pseudotetrahedral iron imido complexes see: Tangen, E.; Conradie, J.; Ghosh, A. J. Chem. Theory Comput. 2007, 3, 448.
-
(2007)
J. Chem. Theory Comput
, vol.3
, pp. 448
-
-
Tangen, E.1
Conradie, J.2
Ghosh, A.3
-
23
-
-
33846068861
-
-
Cowley, R. E.; Bontchev, R. P.; Duesler, E. N.; Smith, J. M. Inorg. Chem. 2006, 45, 9771.
-
(2006)
Inorg. Chem
, vol.45
, pp. 9771
-
-
Cowley, R.E.1
Bontchev, R.P.2
Duesler, E.N.3
Smith, J.M.4
-
24
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40949117370
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In THF, E1/2, 0.64 V. For the related bis(phosphino)pyrazolylborate complex [PhBPtBu 2(pz)Fe≡NAd]B(3,5-(CF3)2C 6H3)4, E1/2, 0.72 V in THF. See ref 3b
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1/2 = -0.72 V in THF. See ref 3b.
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26
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1542280601
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(b) Chan, M.-S.; DeRoos, J. B.; Wahl, A. C. J. Phys. Chem. 1973, 77, 2163.
-
(1973)
J. Phys. Chem
, vol.77
, pp. 2163
-
-
Chan, M.-S.1
DeRoos, J.B.2
Wahl, A.C.3
-
28
-
-
0000686728
-
-
(d) Yang, E. S.; Chan, M.-S.; Wahl, A. C. J. Phys. Chem. 1980, 84, 3094.
-
(1980)
J. Phys. Chem
, vol.84
, pp. 3094
-
-
Yang, E.S.1
Chan, M.-S.2
Wahl, A.C.3
-
29
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33645506119
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a's of these weak acids in MeCN have been extrapolated from the experimentally determined values in DMSO. See Kütt, A.; Leito, I.; Kaljurand, I.; Sooväli, L.; Vlasov, V. M.; Yagupolskii, L. M.; Koppel, I. A. J. Org. Chem. 2006, 71, 2829.
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a's of these weak acids in MeCN have been extrapolated from the experimentally determined values in DMSO. See Kütt, A.; Leito, I.; Kaljurand, I.; Sooväli, L.; Vlasov, V. M.; Yagupolskii, L. M.; Koppel, I. A. J. Org. Chem. 2006, 71, 2829.
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30
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40949153209
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a's of the weak acids. See SI for details.
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a's of the weak acids. See SI for details.
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31
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40949128480
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1/2 + 59.5 in MeCN. Parker, V. D.; Handoo, K. L.; Roness, F.; Tilset M. J. Am. Chem. Soc. 1991, 113, 7493.
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1/2 + 59.5 in MeCN. Parker, V. D.; Handoo, K. L.; Roness, F.; Tilset M. J. Am. Chem. Soc. 1991, 113, 7493.
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-
32
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0001413712
-
-
Bordwell, G. F.; Cheng, J.-P.; Ji, G.-Z.; Satish, A. V.; Zhang, X. J. Am. Chem. Soc. 1991, 113, 9790.
-
(1991)
J. Am. Chem. Soc
, vol.113
, pp. 9790
-
-
Bordwell, G.F.1
Cheng, J.-P.2
Ji, G.-Z.3
Satish, A.V.4
Zhang, X.5
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33
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40949089873
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Anthracene and 1-adamantylamine (51 ± 9% yield) were determined by GC/FID. See SI for details.
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Anthracene and 1-adamantylamine (51 ± 9% yield) were determined by GC/FID. See SI for details.
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34
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a is provided in the SI
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a is provided in the SI.
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(2007)
Proc. Natl. Acad. Sci. U.S.A
, vol.104
, pp. 19181
-
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Sastri, C.V.1
Lee, J.2
Oh, K.3
Lee, Y.J.4
Lee, J.5
Jackson, T.A.6
Ray, K.7
Hirao, H.8
Shin, W.9
Halfen, J.A.10
Kim, J.11
Que Jr., L.12
Shaik, S.13
Nam, W.14
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