Photocatalytic activity of anatase and rutile TiO2 epitaxial thin film grown by pulsed laser deposition

Thin Solid Films

Volumn 564, Issue , 2014, Pages 146-155

  Luttrell, Tim ^a   Halpegamage, Sandamali ^a   Sutter, Eli ^b   Batzill, Matthias ^a  

^a UNIVERSITY OF SOUTH FLORIDA   (United States)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

Anatase; Atomic force microscopy; Epitaxial films; Photocatalysis; Pulsed laser deposition; Rutile; Titanium dioxide; Transmission electron microscopy

Indexed keywords

ANNEALING; ATOMIC FORCE MICROSCOPY; AZO DYES; EPITAXIAL FILMS; INTERFACES (MATERIALS); OXIDE MINERALS; PHOTOCATALYSIS; PULSED LASER DEPOSITION; SINGLE CRYSTALS; TITANIUM DIOXIDE; TRANSMISSION ELECTRON MICROSCOPY; VACUUM;

EPITAXIAL THIN FILMS; HIGH-QUALITY FILMS; HIGH-TEMPERATURE ANNEALING; METHYL ORANGE SOLUTION; PHOTOCATALYTIC ACTIVITIES; POSTGROWTH ANNEALING; RUTILE; SUBSTRATE INTERFACE;

EPITAXIAL GROWTH;

EID: 84904042951     PISSN: 00406090     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tsf.2014.05.058     Document Type: Article

References (65)

1. B.S. Jeong, J.D. Budai, and D.P. Norton Epitaxial stabilization of single crystal anatase films via reactive sputter deposition Thin Solid Films 422 2002 166
2. 3 substrates using reactive molecular beam epitaxy J. Cryst. Growth 310 2008 545
3. 3 and yttria-stabilized zirconia substrates by electron beam evaporation Thin Solid Films 515 2007 3439
4. 3 Phil. Mag. A 82 2002 735
5. 3 substrate by laser molecular-beam epitaxy Appl. Phys. Lett. 78 2001 2664
6. 2 films Appl. Phys. Lett. 80 2002 1174
7. 3 substrates by laser ablation Thin Solid Films 441 2003 140
8. 3(100) prepared using pulsed laser deposition Thin Solid Films 515 2006 535
9. 3 substrates Appl. Phys. Lett. 101 2012 191602
10. 3 J. Nanopart. Res. 15 2013 1735
11. 2 films prepared by pulsed laser deposition J. Cryst. Growth 237 2002 569
12. 3 J. Cryst. Growth 312 2009 149
13. 2 on r-plane sapphire J. Vac. Sci. Technol. A 27 2009 230
14. 3 Thin Solid Films 484 2005 132
15. 3(001) Thin Solid Films 418 2002 197
16. 2(001): reconstruction, atomic steps, and domains Phys. Rev. B 63 2001 235402
17. 2(001)-(1 × 4) surface Phys. Rev. Lett. 87 2001 266105
18. Y. Wang, H.J. Sun, S.J. Tan, H. Feng, Z.W. Cheng, J. Zhao, A.D. Zhao, B. Wang, Y. Luo, J.L. Yang, and J.G. Hou Role of point defects on the reactivity of reconstructed anatase titanium dioxide (001) surface Nat. Commun. 4 2013 2214
19. 3(001) Surf. Sci. 606 2012 1443
20. J.M.D. Coey, M. Venkatesan, and C.B. Fitzgerald Donor impurity band exchange in dilute ferromagnetic oxides Nat. Mater. 4 2005 173
21. J.M.D. Coey, and S.A. Chambers Oxide dilute magnetic semiconductors - fact or fiction? MRS Bull. 33 2008 1053
22. 2 thin films Phys. Rev. B 70 2004 195204
23. Y. Matsumoto, M. Murakami, T. Shono, T. Hasegawa, T. Fukumura, M. Kawasaki, P. Ahmet, T. Chikyow, S. Koshihara, and H. Koinuma Room-temperature ferromagnetism in transparent transition metal-doped titanium dioxide Science 291 2001 854
24. 2 anatase Appl. Phys. Lett. 79 2001 3467
25. 2 films Phys. B Condens. Matter 370 2005 46
26. 2:Co anatase thin films by sputtering technique J. Magn. Magn. Mater. 272 2004 E1537
27. P.A. Stampe, R.J. Kennedy, Y. Xin, and J.S. Parker Investigation of the cobalt distribution in the room temperature ferromagnet TiO2: Co J. Appl. Phys. 93 2003 7864
28. 2 anatase Appl. Phys. Lett. 82 2003 1257
29. 2 dilute magnetic semiconductor thin films J. Appl. Phys. 106 2009 043913
30. 2 thin films Appl. Surf. Sci. 254 2007 365
31. 2 thin films Appl. Phys. Lett. 84 2004 2602
32. 2 thin films from magnetic force microscopy measurements J. Appl. Phys. 97 2005 10D323
33. 2 anatase: A ferromagnetic insulator J. Appl. Phys. 97 2005 046103
34. 2 thin films: clusters or not? Appl. Phys. Lett. 85 2004 6212
35. 3 substrates by laser ablation Appl Appl. Phys. Lett. 84 2004 2850
36. 3 by rf sputtering Appl. Surf. Sci. 225 2009 8104
37. 2 epitaxial films Phys. Rev. B 79 2009 165108
38. 2 as a transparent conducting oxide Thin Solid Films 516 2008 4133
39. 2: intrinsic transparent metallic anatase versus highly resistive rutile phase J. Appl. Phys. 102 2007 013701
40. D. Kurita, S. Ohta, K. Sugiura, H. Ohta, and K. Koumoto Carrier generation and transport properties of heavily Nb-doped anatase TiO2 epitaxial films at high temperatures J. Appl. Phys. 100 2006 096105
41. 2 epitaxial film as transparent conducting oxide Jpn. J. Appl. Phys. 44 2005 L1063
42. 2: Ta doping or alloying? Appl. Phys. Lett. 98 2011 072111
43. 2 photocatalysis and related surface phenomena Surf. Sci. Rep. 63 2008 515
44. 2 surfaces - principles, mechanisms, and selected results Chem. Rev. 95 1995 735
45. 2 photocatalysis Surf. Sci. Rep. 66 2011 185
46. 3(001) Surf. Sci. 602 2008 133
47. T. Okato, T. Sakano, and M. Obara Suppression of photocatalytic efficiency in highly N-doped anatase films Phys. Rev. B 72 2005 115124
48. 2 films grown using a free-radical nitrogen oxide source J. Appl. Phys. 97 2005 123511
49. 3 heterostructures Appl. Surf. Sci. 252 2007 2603
50. 2 electrodes J. Phys. Chem. B 109 2005 24441
51. 2 film Chem Phys. Lett. 407 2005 209
52. 2 nanocrystals: comparison of anatase, rutile, and brookite polymorphs and exploration of surface chemistry ACS Catal. 2 2012 1817
53. 2 films Sci Sci. Rep. 4 2014 4043
54. 2 surfaces J. Phys. Chem. B 102 1998 3216
55. 2(011)-(2 × 1) Phys. Rev. Lett. 93 2004 036104
56. 2(011)-(2 × 1) leads to one-dimensional nanocluster formation Phys. Rev. Lett. 108 2012 106105
57. 2 thin films Phys Phys. Rev. B 86 2012 104110
58. U. Diebold The surface science of titanium dioxide Surf. Sci. Rep. 48 2003 53
59. L. Liborio, and N. Harrison Thermodynamics of oxygen defective Magneli phases in rutile: A first-principles study Phys. Rev. B 77 2008 104104
60. M. Batzill Fundamental aspects of surface engineering of transition metal oxide photocatalysts Energy. Environ. Sci. 4 2011 3275
61. 2(110) Surf. Rev. Lett. 7 2000 613
62. 2 photocatalyst for environmental applications J. Photochem. Photobiol. C 15 2013 1
63. M. Xing, J. Zhang, F. Chen, and B. Tian An economic method to prepare vacuum activated photocatalysts with high photo-activities and photosensitivities Chem. Commun. 47 2011 4947
64. 2-based photocatalysts to be active in visible light Chem. Commun. 21 2004 2476
65. T. Kakp, N. Umezawa, K. Xie, and J. Ye Undoped visible-light-sensitive titania photocatalyst J. Mater. Sci. 48 2013 108