Ruthenium-catalyzed ortho-selective aromatic CH alkenylation with alkenyl carbonates

Chemistry Letters

Volumn 43, Issue 5, 2014, Pages 667-669

  Ogiwara, Yohei ^a   Kochi, Takuya ^a   Kakiuchi, Fumitoshi ^a,b  

^a KEIO UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 84899850246     PISSN: 03667022     EISSN: 13480715     Source Type: Journal    
DOI: 10.1246/cl.140006     Document Type: Article

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47. In the case of the reaction using alkenyl acetate as an alkenylating agent, the Z-isomer reacted faster than the Eisomer (See ref 8b). Although the difference in reactivity between E-and Z-carbonate 1 is not clear, when the reaction was performed using 1b (Table 1, Entry 4), the ratio of the Z-isomer in the remaining 1b slightly decreased from that of the starting 1b (E:Z = 32:68 to 36:64). 10 The reduction of 3a was observed when the reaction of 3a with 2b and 1b was performed in the presence of [Ru(cot)(cot)] as a catalyst. See the Supporting Information for details. Supporting Information is available electronically on the CSJ-Journal Web site, http://www.csj.jp/journals/chem- lett/index.html.