The Ru(cod)(cot)-catalyzed alkenylation of aromatic C-H bonds with alkenyl acetates

Journal of the American Chemical Society

Volumn 129, Issue 32, 2007, Pages 9858-9859

  Matsuura, Yusuke ^b   Tamura, Masaru ^a   Kochi, Takuya ^a   Sato, Mitsuo ^a   Chatani, Naoto ^b   Kakiuchi, Fumitoshi ^a  

^a KEIO UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1,3,5 CYCLOOCTATRIENE; 1,5 CYCLOOCTADIENE; ACETIC ACID DERIVATIVE; ALKADIENE; ALKENE; AROMATIC COMPOUND; CARBON; HYDROGEN; RUTHENIUM; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BINDING; COUPLING REACTION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 34547911383     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja071965m     Document Type: Article

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33. See Supporting Information for further details on mechanistic studies.
34. 3-catalyzed reaction of arylpyridines with allyl acetates gave a mixture of ortho allylation and alkenylation products. We believe the mechanism of this reaction is different from our reaction described here due to much lower catalytic activity of our reaction under Oi's reaction conditions. See Supporting Information for further details: Oi, S.; Tanaka, Y.; Inoue, Y. Organometallics 2006, 25, 4773-4778.