Nonheme iron mediated oxidation of light alkanes with oxone: Characterization of reactive oxoiron(IV) ligand cation radical intermediates by spectroscopic studies and DFT calculations

Angewandte Chemie - International Edition

Volumn 53, Issue 3, 2014, Pages 798-803

  Tse, Chun Wai ^a   Chow, Toby Wai Shan ^a   Guo, Zhen ^a   Lee, Hung Kay ^c   Huang, Jie Sheng ^a   Che, Chi Ming ^a,b  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

^b UNIVERSITY OF HONG KONG   (China)

^c CHINESE UNIVERSITY OF HONG KONG   (Hong Kong)

Author keywords

alkanes; iron; nonheme iron complexes; oxidation; oxoiron complexes

Indexed keywords

CATALYSIS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ETHANE; HYDROCARBONS; IRON; IRON METALLOGRAPHY; LIGANDS; OXIDATION; PARAFFINS; POSITIVE IONS; PROPANE; REACTION INTERMEDIATES; SPECTROSCOPIC ANALYSIS; ULTRAVIOLET VISIBLE SPECTROSCOPY;

CATALYTICALLY ACTIVE SPECIES; CATIONIC INTERMEDIATES; IRON-CATALYZED OXIDATIONS; NON-HEME IRON ENZYMES; NONHEME IRON COMPLEXES; OXOIRON; SPECTROSCOPIC STUDIES; UV/ VIS SPECTROSCOPY;

IRON COMPOUNDS;

ALKANE; COORDINATION COMPOUND; CYCLOHEXANE DERIVATIVE; IRON; LIGAND; POTASSIUM PEROXYMONOSULFURIC ACID; SULFURIC ACID;

ARTICLE; CHEMISTRY; ELECTRON SPIN RESONANCE; NONHEME IRON COMPLEXES; OXIDATION; OXIDATION REDUCTION REACTION; OXOIRON COMPLEXES; QUANTUM THEORY; SYNTHESIS;

ALKANES; IRON; NONHEME IRON COMPLEXES; OXIDATION; OXOIRON COMPLEXES;

ALKANES; COORDINATION COMPLEXES; CYCLOHEXANES; ELECTRON SPIN RESONANCE SPECTROSCOPY; IRON; LIGANDS; OXIDATION-REDUCTION; QUANTUM THEORY; SULFURIC ACIDS;

EID: 84891878310     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201305153     Document Type: Article

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