Fluxional cyclic seleninate ester: NMR and computational studies, glutathione peroxidase-like behavior, and unexpected rearrangement

Journal of Organic Chemistry

Volumn 78, Issue 20, 2013, Pages 10369-10382

  McNeil, Nicole M R ^a   Matz, Marie C ^a   Back, Thomas G ^a  

^a UNIVERSITY OF CALGARY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

COMPUTATIONAL STUDIES; CROSSOVER EXPERIMENTS; DEACTIVATION PATHWAYS; FLUXIONAL BEHAVIOR; INTRAMOLECULAR REARRANGEMENT; PEROXIDASE-LIKE ACTIVITIES; SELENINATE ESTERS; VARIABLE-TEMPERATURE NMR;

ACTIVATION ENERGY; CATALYSIS; ESTERS; HYDROGEN PEROXIDE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PEPTIDES; PEROXIDES;

ESTERIFICATION;

7 (HYDROXYMETHYL) 3H 2,1 LAMBDA 4 BENZOXASELENO 1 ONE; CYCLIC SELENINATE ESTER; DIBENZYL DISULFIDE; ESTER; GLUTATHIONE PEROXIDASE; HYDROGEN PEROXIDE; HYDROXYL GROUP; SELENENYL SULFIDE; SELENIDE; SELENIUM; SELENURANE; TRIFLUOROACETIC ACID; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; ENZYME ACTIVITY; NUCLEAR MAGNETIC RESONANCE; OXIDATION; ROOM TEMPERATURE;

BENZYL COMPOUNDS; CATALYSIS; GLUTATHIONE PEROXIDASE; HYDROGEN PEROXIDE; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; ORGANOSELENIUM COMPOUNDS; OXIDATION-REDUCTION; SULFHYDRYL COMPOUNDS; SULFIDES;

EID: 84886431024     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo401757m     Document Type: Article

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