Synthesis of anionic hypervalent cyclic selenenate esters: Relevance to the hypervalent intermediates in nucleophilic substitution reactions at the selenium (II) center

Chemistry - A European Journal

Volumn 18, Issue 5, 2012, Pages 1444-1457

  Selvakumar, Karuthapandi ^a   Singh, Harkesh B ^a   Goel, Nidhi ^b   Singh, Udai P ^b   Butcher, Ray J ^c  

^a INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

^b INDIAN INSTITUTE OF TECHNOLOGY ROORKEE   (India)

^c HOWARD UNIVERSITY   (United States)

Author keywords

Cyclization; Hypervalent compounds; Nucleophilic substitution; Selenenate esters; Selenium

Indexed keywords

ACID GROUPS; BIPYRIDINES; CARBOXYLATE GROUPS; CYCLIZATION REACTIONS; DFT-B3LYP; DIARYL DISELENIDES; HYPERVALENT COMPOUNDS; INTRAMOLECULAR CYCLIZATIONS; LOW TEMPERATURES; MODEL REACTIONS; NEUTRAL DONOR; NUCLEOPHILIC SUBSTITUTION REACTIONS; NUCLEOPHILIC SUBSTITUTIONS; ORGANIC BASIS; ORGANIC CATIONS; PYRIDINIUM; STRUCTURAL FEATURE; STRUCTURAL STUDIES; X-RAY STRUCTURE;

CARBOXYLATION; CARBOXYLIC ACIDS; CYCLIZATION; ESTERIFICATION; METHANOL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; REACTION INTERMEDIATES; SELENIUM; SELENIUM COMPOUNDS; SUBSTITUTION REACTIONS;

ESTERS;

ANION; DICARBOXYLIC ACID; ESTER; ORGANOSELENIUM DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; CYCLIZATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ANIONS; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; DICARBOXYLIC ACIDS; ESTERS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; ORGANOSELENIUM COMPOUNDS; STEREOISOMERISM;

EID: 84857183350     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201003725     Document Type: Article

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