Mechanistic studies on the Pd-catalyzed vinylation of aryl halides with vinylalkoxysilanes in water: The effect of the solvent and NaOH promoter

Journal of the American Chemical Society

Volumn 135, Issue 37, 2013, Pages 13749-13763

  Gordillo, Alvaro ^a   Ortuño, Manuel A ^b   López Mardomingo, Carmen ^a   Lledós, Agustí ^b   Ujaque, Gregori ^b   De Jesús, Ernesto ^a  

^a UNIVERSITY OF ALCALÁ   (Spain)

^b UNIVERSITAT AUTÒNOMA DE BARCELONA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC CYCLES; CATALYTIC PRECURSORS; HIGH TEMPERATURE; HIYAMA CROSS COUPLINGS; HYDROLYTIC DESILYLATION; MECHANISTIC STUDIES; NUCLEOPHILICITIES; REDUCTIVE ELIMINATION;

CATALYSIS; METAL HALIDES; OLEFINS; SILICON;

SOLVENTS;

HALIDE; HYDROGEN; PALLADIUM; SILANE DERIVATIVE; SODIUM HYDROXIDE; SOLVENT; VINYL DERIVATIVE; WATER;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; COMPUTER ANALYSIS; CONTROLLED STUDY; CROSS COUPLING REACTION; DESILYLATION; ENERGY; HECK REACTION; HIGH TEMPERATURE PROCEDURES; HYDROGEN BOND; HYDROLYSIS; METALLATION; NUCLEOPHILICITY; PRECURSOR; VINYLATION;

CATALYSIS; MOLECULAR STRUCTURE; PALLADIUM; SILANES; SODIUM HYDROXIDE; SOLUBILITY; STEREOISOMERISM; VINYL COMPOUNDS; WATER;

EID: 84884484235     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja404255u     Document Type: Article

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