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Volumn 25, Issue 22, 2006, Pages 5449-5455

Competition of insertion and transmetalation pathways in the reactions of alkenylsilanes with aryl complexes of palladium(II). An experimental study

Author keywords

[No Author keywords available]

Indexed keywords

MOLECULAR STRUCTURE; OLEFINS; PALLADIUM COMPOUNDS; POSITIVE IONS; REACTION KINETICS; SUBSTITUTION REACTIONS;

EID: 33751401523     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060622e     Document Type: Article
Times cited : (12)

References (53)
  • 6
    • 0346387650 scopus 로고    scopus 로고
    • Current Methods in Inorganic Chemistry Yamamoto, A., Kurosawa, H., Eds.; Elsevier: Lausanne, Chapter 6
    • Espinet, P.; Albéniz, A. C. In Fundamentals of Molecular Catalysis: Current Methods in Inorganic Chemistry Vol. 3; Yamamoto, A., Kurosawa, H., Eds.; Elsevier: Lausanne, 2003; Chapter 6.
    • (2003) Fundamentals of Molecular Catalysis , vol.3
    • Espinet, P.1    Albéniz, A.C.2
  • 9
    • 0000185390 scopus 로고
    • (c) Horn, K. A. Chem. Rev. 1995, 95, 1317-1350.
    • (1995) Chem. Rev. , vol.95 , pp. 1317-1350
    • Horn, K.A.1
  • 36
    • 33751417171 scopus 로고    scopus 로고
    • note
    • 19F NMR spectra (see Experimental Section).
  • 41
    • 33751420843 scopus 로고    scopus 로고
    • note
    • 2, were formed. 2-Phenylpropene was also reacted with complex 4, and only the products of 2,1 insertion were observed.
  • 49
    • 33751437551 scopus 로고    scopus 로고
    • note
    • 3 solution of this silane.
  • 51
    • 33751429278 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum is not reached at this temperature, and only extremely broad signals for the coordinated allylsilane are observed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.