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Volumn 348, Issue 7-8, 2006, Pages 945-952

Solvent-less and fluoride-free Hiyama reaction of arylsiloxanes with aryl bromides and chlorides promoted by sodium hydroxide: A useful protocol for palladium recycling and product isolation

Author keywords

Arylsiloxanes; Biaryls; Cross coupling; Microwave heating; Palladacycles

Indexed keywords


EID: 33744814897     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200505494     Document Type: Article
Times cited : (83)

References (65)
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    • For applications of palladacycles 1 and 2 in organic synthesis, see: a) biaryl sulfones by Suzuki reaction: A. Costa, C. Nájera, J. M. Sansano, J. Org. Chem. 2002, 67, 5216-5225;
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    • note
    • [8e]
  • 60
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    • note
    • Microwave reactions were performed with a CEM Discover Synthesis Unit (CEM Corp., Matthews, NC) with a continuous focused microwave power delivery system in glass vessels (10 mL) sealed with a septum under magnetic stirring. The temperature of the reaction mixture inside the vessel was monitored using a calibrated infrared temperature control under the reaction vessel.
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    • It is known that TBAB stabilizes colloidal palladium nanoparticles acting as catalysts in cross-coupling reactions: R. T. Reetz, E. Westermann, Angew. Chem. Int. Ed. 2000, 59, 165-168.
    • (2000) Angew. Chem. Int. Ed. , vol.59 , pp. 165-168
    • Reetz, R.T.1    Westermann, E.2
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    • Eur. Patt. Appl. EPXXDW EP 470391 A1 19920212, 1992
    • 3-(4-Tolyl)pyridine (5fd) has been described as a perfume and aroma ingredient: A. F. Thomas, F. Bassols, Eur. Patt. Appl. EPXXDW EP 470391 A1 19920212, 1992;
    • Thomas, A.F.1    Bassols, F.2
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.