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Volumn 3, Issue 9, 2011, Pages 1413-1418

Turnover numbers and soluble metal nanoparticles

Author keywords

Heterogeneous catalysis; Homogeneous catalysis; Nanoparticles; Surface analysis; Turnover number

Indexed keywords


EID: 80052828787     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201100159     Document Type: Article
Times cited : (109)

References (44)
  • 3
    • 80052838309 scopus 로고    scopus 로고
    • TOF/TON is defined in the IUPAC Gold book as turnover frequency (in catalysis), commonly called the turnover number, N, and defined, as in enzyme catalysis, as molecules reacting per active site in unit time. IUPAC. Compendium of Chemical Terminology, 2nded., Eds.: A.D. McNaught, A. Wilkinson), Blackwell Science Oxford, 1997. This definition was introduced in the 1975 rules of the Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis, Pure Appl. Chem. 1976, 46, 71-90. The original text warns that this "can be a useful concept if employed with care. In view of the problems in measuring the number of active sites discussed [...], it is important to specify exactly the means used to express the quantity of catalyst in terms of active sites."
    • TOF/TON is defined in the IUPAC Gold book as turnover frequency (in catalysis), commonly called the turnover number, N, and defined, as in enzyme catalysis, as molecules reacting per active site in unit time. IUPAC. Compendium of Chemical Terminology, 2nded., (Eds.: A.D. McNaught, A. Wilkinson), Blackwell Science Oxford, 1997. This definition was introduced in the 1975 rules of the Definitions, Terminology and Symbols in Colloid and Surface Chemistry. Part II: Heterogeneous Catalysis, Pure Appl. Chem. 1976, 46, 71-90. The original text warns that this "can be a useful concept if employed with care. In view of the problems in measuring the number of active sites discussed [...], it is important to specify exactly the means used to express the quantity of catalyst in terms of active sites."
  • 11


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.