On the mechanism of cine substitution in the Stille reaction: New evidence for the intermediacy of Pd(0) carbenes

Tetrahedron Letters

Volumn 37, Issue 39, 1996, Pages 6997-7000

  Farina, Vittorio ^a   Azad Hossain, M ^a  

^a BOEHRINGER INGELHEIM PHARMACEUTICALS INC   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE;

ARTICLE; CATALYSIS; DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0030599267     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)01568-7     Document Type: Article

References (18)

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3. (c) Farina, V.; Roth, G.P. in Advances in Metal-Organic Chemistry, Liebeskind, L.S., Ed.; JAI Press, 1995, 5, 1.
4. 2. Kikukawa, K.; Umekawa, H.; Matsuda, T. J. Organomet. Chem. 1986, 311, C44.
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7. (c) for cine substitution of vinylzinc compounds, see Ennis, D.S.; Gilchrist, T.L. Tetrahedron Lett. 1989, 30, 3735;
8. (d) for cine substitution of vinylboron compounds, see Hunt, A.R.; Stewart, S.K.; Whiting, A. Tetrahedron Lett. 1993, 34, 3599.
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10. 5. Stang, P.J.; Hanack, M.C.; Subramanian, L.R. Synthesis 1982, 85.
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12. 7. Farina, V.; Krishnan, B. J. Am. Chem. Soc. 1991, 113, 9585.
13. 8. Thorn, D.L.; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 2079.
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15. (b) Rautenstrauch, V. Tetrahedron Lett. 1984, 25, 3845;
16. (c) Trost, B.M.; Hashmi, A.S.K. Angew. Chem. Int. Ed. Engl. 1993, 32, 1085.
17. 10. Monteiro, N.; Goré, J.; Van Hemelryck, B.; Balme, G. Synlett 1994, 447.
18. 13CNMR and mass spectroscopy, as well as elemental analysis (C,H).