Mild rhodium(III)-catalyzed cyclization of amides with α,β- unsaturated aldehydes and ketones to azepinones: Application to the synthesis of the homoprotoberberine framework

Angewandte Chemie - International Edition

Volumn 52, Issue 20, 2013, Pages 5393-5397

  Shi, Zhuangzhi ^a   Grohmann, Christoph ^a   Glorius, Frank ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

amides; azepinones; C H activation; homoprotoberberines; rhodium

Indexed keywords

AZEPINONES; C-H ACTIVATION; HOMOPROTOBERBERINES; RHODIUM (III); RING SYSTEMS; SEVEN-MEMBERED RINGS; UNSATURATED ALDEHYDES;

ACTIVATION ANALYSIS; AMIDES; KETONES; RHODIUM;

CYCLIZATION;

ALDEHYDE; AZEPINE DERIVATIVE; BENZAMIDE DERIVATIVE; BERBERINE DERIVATIVE; KETONE; PROTOBERBERINE; RHODIUM;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CYCLIZATION; CYCLOADDITION; HYDROGEN BOND; STEREOISOMERISM; SYNTHESIS;

ALDEHYDES; AZEPINES; BENZAMIDES; BERBERINE ALKALOIDS; CATALYSIS; CYCLIZATION; CYCLOADDITION REACTION; HYDROGEN BONDING; KETONES; MOLECULAR STRUCTURE; RHODIUM; STEREOISOMERISM;

EID: 84877257345     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201301426     Document Type: Article

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