Asymmetric dearomatizing spirolactonization of naphthols catalyzed by spirobiindane-based chiral hypervalent iodine species

Journal of the American Chemical Society

Volumn 135, Issue 11, 2013, Pages 4558-4566

  Dohi, Toshifumi ^a   Takenaga, Naoko ^b   Nakae, Tomofumi ^a   Toyoda, Yosuke ^a   Yamasaki, Mikio ^c   Shiro, Motoo ^c   Fujioka, Hiromichi ^b   Maruyama, Akinobu ^b   Kita, Yasuyuki ^a  

^a RITSUMEIKAN UNIVERSITY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c RIGAKU CORPORATION   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CATALYTIC OXIDATION; ENANTIOSELECTIVITY; IODINE; NAPHTHOL; REACTION INTERMEDIATES; STEREOCHEMISTRY; STEREOSELECTIVITY; X RAY ANALYSIS;

ASYMMETRIC INDUCTION; HYPERVALENT IODINE CHEMISTRY; HYPERVALENT IODINE COMPOUNDS; HYPERVALENT IODINE REAGENTS; STEREOSELECTIVE CONSTRUCTION; STEREOSELECTIVE FORMATION; STRUCTURAL ELUCIDATION; TRANSITION STATE MODELING;

IODINE COMPOUNDS;

1 NAPHTHOL DERIVATIVE; 3' PHENYLSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 4' BENZYLSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 4' BROMOSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 4' METHOXYSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 4' PHENYLSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 5' AZIDOSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 5' BENZYLOXYSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 5' BROMOSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 5' PHENYLSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 6' AZIDOSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 6' PHENYLSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; 8' METHYLSPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; IODINE; SPIRO COMPOUND; SPIROBIINDANE; SPIRO[TETRAHYDROFURAN 2,2' (1'H NAPHTHALENE)] 1',5 DIONE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC CATALYSIS; CATALYST; CHEMICAL REACTION; COVALENT BOND; ENANTIOSELECTIVITY; OXIDATION; SPIROLACTONIZATION; STEREOCHEMISTRY; X RAY ANALYSIS;

EID: 84875449090     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja401074u     Document Type: Article

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