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Diploma thesis, Universität Basel 2-Iodobenzoylchloride was treated with chiral alcohols (borneol) or amines (phenylalanine methylester; 1-phenylethylamine) to yield the corresponding esters resp. amides, which were then transformed into the hypervalent hydroxy(tosyloxy)iodo compounds. In the reactions mentioned in the text no selectivities were obtained with these reagents
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Hirt, U. H. Diploma thesis, Universität Basel 1996. 2-Iodobenzoylchloride was treated with chiral alcohols (borneol) or amines (phenylalanine methylester; 1-phenylethylamine) to yield the corresponding esters resp. amides, which were then transformed into the hypervalent hydroxy(tosyloxy)iodo compounds. In the reactions mentioned in the text no selectivities were obtained with these reagents.
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note
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0028272208
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Compound 7 was found to have 80% ee
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3SnH, AIBN) was compared with the literature value (Seebach, D.; Beck, A. K.; Schmidt, B.; Wang, Y. M. Tetrahedron 1994, 50, 4363-4368). Compound 7 was found to have 80% ee.
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0141688559
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The absolute configuration was determined by synthesis of ent-10 from (S)-(-)-lactic acid: Imfeld, M.; Suchy, M.; Vogt, P. Kucác, T.; Schlageter, M.; Widmer, E. Helv. Chim. Acta 1982, 65, 1233-1241.
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