Novel catalytic asymmetric sulfoxidation in water using the hypervalent iodine reagent iodoxybenzene

Chemical and Pharmaceutical Bulletin

Volumn 48, Issue 3, 2000, Pages 445-446

  Tohma, Hirofumi ^a   Takizawa, Shinobu ^a   Morioka, Hironori ^a   Maegawa, Tomohiro ^a   Kita, Yasuyuki ^a  

^a OSAKA UNIVERSITY   (Japan)

Author keywords

Asymmetric oxidation; Hypervalent iodine reagent; Sulfoxide; Water

Indexed keywords

BENZENE DERIVATIVE; CYCLODEXTRIN; IODINE; SULFIDE; SULFOXIDE; WATER;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; OXIDATION; REACTION ANALYSIS;

EID: 0034034737     PISSN: 00092363     EISSN: None     Source Type: Journal    
DOI: 10.1248/cpb.48.445     Document Type: Article

References (22)

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21. The ee values when using other chiral sources are as follows: di(2-MeO)benzoyl-D-tartaric acid (34% ee), di(2-toluoyl)-D-tartaric acid (14% ee), dipivaloyl-D-tartaric acid (13% ee), di(2-naphthoyl)-D-tartaric acid (24% ee), (S)-(+)-α-methoxyphenylacetic acid (14% ee), (+)-10-camphorsulfonic acid (0% ee), N-phthaloyl-D-glutamic acid (16% ee), and (S)-(+)-1,1′-binaphthyl-2,2′-diyl hydrogenphosphate (0% ee).
22. 4,8)