RCNSSS+: A novel class of stable sulfur rich radical cations

Coordination Chemistry Reviews

Volumn 257, Issue 5-6, 2013, Pages 1067-1091

  Shuvaev, Konstantin V ^a   Passmore, Jack ^a  

^a UNIVERSITY OF NEW BRUNSWICK   (Canada)

Author keywords

1,2,3,4 Trithiazolium; Dimerization; Diradicals; EPR; Main group; Molecular magnetism; Stable radicals; Triplet excited state

Indexed keywords

EID: 84872872535     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ccr.2012.07.003     Document Type: Review

References (294)

1. Fremy E. Ann. Chim. Phys. 1845, 15:459.
2. Würster C., Sendtner R. Chem. Ber. 1879, 12:12.
3. Würster C. Chem. Ber. 1879, 12:2071.
4. Demarcay E. Compt. Rend. 1880, 91:854.
5. Howie R.A., Glasser L.S.D., Maser W.J. J. Chem. Soc. A 1968, 3043.
6. De Boer J.L., Vos A., Huml K. Acta Cryst. B 1968, 24:542.
7. Small R.W.H., Banister A.J., Hauptman Z.V. J. Chem. Soc. Dalton Trans. 1984, 1377.
8. Gomberg M. J. Am. Chem. Soc. 1900, 22:757.
9. Tidwell T. Stable Radicals Fundamentals and Applied Aspects of Odd-electron Compounds 2010, 1-28. John Wiley & Sons, Ltd, Wiltshire, and references therein. R.G. Hicks (Ed.).
10. Griller D., Ingold K.E. Acc. Chem. Res. 1976, 9:13.
11. Huheey J.E. Inorganic Chemistry: Principles of Structure and Reactivity 1978, Harper and Row, New York.
12. The anomalously low bond energies of single OO and NN bonds is attributed to extra intra-electronic repulsion inside O and N atoms, even in the absence of an adjacent atom, and expresses itself in their reluctance to accept an additional electron whether it comes from the like or another atom. The electron affinities of oxygen and nitrogen atoms are 88 and 25-33kJ/mol, respectively, which is lower than expected based on the comparison with the heavier congeners sulfur and phosphorus, see:.
13. Politzer P. Inorg. Chem. 1977, 16:3350.
14. Politzer P. J. Am. Chem. Soc. 1969, 91:6235.
15. Chivers T. A Guide to Chalcogen-Nitrogen Chemistry 2004, World Scientific, Singapore.
16. Wheeler M.D., Newman S.M., Orr-Ewing A.J. J. Chem. Phys. 1998, 108:6594.
17. Lundegaard L.F., Weck G., McMahon M.I., Desgreniers S., Loubeyre P. Nature 2006, 443:201.
18. Brownridge S., Crawford M.-J., Du H., Harcourt R.D., Knapp C., Laitinen R.S., Passmore J., Rautiainen J.M., Suontamo R.J., Valkonen J. Inorg. Chem. 2007, 46:681.
19. Parsons S., Passmore J. Inorg. Chem. 1992, 31:526.
20. Banister A.J., Gorrell I.B. Adv. Mater. 1998, 10:1415.
21. Hassanzadeh P., Andrews L. J. Am. Chem. Soc. 1992, 114:83.
22. Keana J.F.W. Chem. Rev. 1978, 78:37.
23. Caneschi A., Gatteschi D., Rey P. Prog. Inorg. Chem. 1991, 39:331.
24. Veciana J., Cirujeda J., Novoa J.J., Deumal M. Magnetic Properties of Organic Materials 1999, Dekker, New York, p. 573.
25. Novoa J.J., Deumal M. Struct. Bond. 2001, 100:33.
26. Mukai K. Magnetic Properties of Organic Materials 1999, Dekker, New York, p. 427.
27. Koivisto B.D., Hicks R.G. Coord. Chem. Rev. 2005, 249:2612.
28. Hicks R.G. Can. J. Chem. 2004, 82:1119.
29. Hicks R.G. Org. Biomol. Chem. 2007, 5:1321.
30. Lahti P. Trends Org. Chem. 1992, 3:179.
31. Mukai K. Bull. Chem. Soc. Jpn. 1969, 42:40.
32. Sugano T. Polyhedron 2001, 20:1285.
33. Altwicker E.R. Chem. Rev. 1967, 67:475.
34. Rawson J.M., Banister A.J., Lavender I. Adv. Het. Chem. 1995, 62:137.
35. Rawson J.M., Palacio F. Struct. Bond. 2001, 100:93.
36. Rawson J.M., Luzon J., Palacio F. Coord. Chem. Rev. 2005, 249:2631.
37. Oakley R.T. Prog. Inorg. Chem. 1988, 36:299.
38. Cordes A.W., Haddon R.C., Oakley R.T. The Chemistry of Inorganic Ring Systems 1992, 295-322. Elsevier, Amsterdam. R. Steudel (Ed.).
39. Rawson J.M., McManus G.D. Coord. Chem. Rev. 1999, 189:135.
40. Rawson J.M., Alberola A., Whalley A. J. Mater. Chem. 2006, 16:2560.
41. Hicks R.G. Stable Radicals Fundamentals and Applied Aspects of Odd-electron Compounds 2010, 317-380. John Wiley & Sons, Ltd, Wiltshire. R.G. Hicks (Ed.).
42. Power P.P. Chem. Rev. 2003, 103:789.
43. Breher F. Coord. Chem. Rev. 2007, 251:1007.
44. Robertson C.M., Myles D.J.T., Leitch A.A., Reed R.W., Dooley B.M., Frank N.L., Dube P.A., Thompson L.K., Oakley R.T. J. Am. Chem. Soc. 2007, 129:12688.
45. Robertson C.M., Leitch A.A., Cvrkalj K., Reed R.W., Myles D.J.T., Dube P.A., Oakley R.T. J. Am. Chem. Soc. 2008, 130:8414.
46. Robertson C.M., Leitch A.A., Cvrkalj K., Myles D.J.T., Reed R.W., Dube P.A., Oakley R.T. J. Am. Chem. Soc. 2008, 130:14791.
47. Winter S.M., Datta S., Hill S., Oakley R.T. J. Am. Chem. Soc. 2011, 133:8126.
48. Leitch A.A., Lekin K., Winter S.M., Downie L.E., Tsuruda H., Tse J.S., Mito M., Desgreniers S., Dube P.A., Zhang S., Liu Q., Jin C., Ohishi Y., Oakley R.T. J. Am. Chem. Soc. 2011, 133:6051.
49. Edwards A.J., Jones G.R. J. Chem. Soc. A 1971, 2318.
50. Gillespie R.J., Kapoor R., Faggiani R., Lock C.J.L., Murchie M., Passmore J. J. Chem. Soc. Chem. Commun. 1983, 8.
51. Faggiani R., Gillespie R.J., Lock C.J.L., Vekris J.E. Inorg. Chem. 1988, 27:4350.
52. Davies C.G., Gillespie R.J., Ireland P.R., Sowa J.M. Can. J. Chem. 1974, 52:2048.
53. Murchie M.P., Johnson J.P., Passmore J., Sutherland G.W., Tajik M., Whidden T.K., White P.S., Grein F. Inorg. Chem. 1992, 31:273.
54. Brownridge S., Krossing I., Passmore J., Jenkins H.D.B., Roobottom H.K. Coord. Chem. Rev. 2000, 197:397.
55. Oakley R.T. Adv. Mater. 1994, 6:798.
56. Oakley R.T. Can. J. Chem. 1993, 1775.
57. Oakley R.T. Phosph. Sulf. Sil. Relat. Elem. 2004, 179:673.
58. Burford N., Passmore J., Schriver M.J. J. Chem. Soc. Chem. Commun. 1986, 140.
59. Du H., Haddon R.C., Krossing I., Passmore J., Rawson J.M., Schriver M.J. J. Chem. Soc. Chem. Commun. 2002, 1836.
60. Brooks W.V.F., Burford N., Passmore J., Schriver M.J., Sutcliffe L.H. J. Chem. Soc. Chem. Commun. 1987, 69.
61. Passmore J., Sun X. Inorg. Chem. 1996, 35:1313.
62. Brownridge S., Haddon R.C., Oberhammer H., Parsons S., Passmore J., Schriver M.J., Sutcliffe L., Westwood N.P.C. J. Chem. Soc. Dalton Trans. 2000, 3365.
63. Fujita W., Awaga K. Science 1999, 286:261.
64. Matsuzaki H., Fujita W., Awaga K., Okamoto H. Phys. Rev. Lett. 2003, 91:017403.
65. McManus G.D., Rawson J.M., Feeder N., van Duijn J., McInnes E.J.L., Novoa J.J., Burriel R., Palacio F., Oliete P. J. Mater. Chem. 2001, 11:1992.
66. Barclay T.M., Cordes A.W., deLaat R.H., Goddard J.D., Haddon R.C., Jeter D.Y., Mawhinney R.C., Oakley R.T., Palstra T.T.M., Patenaude G.W., Reed R.W., Westwood N.P.C. J. Am. Chem. Soc. 1997, 119:2633.
67. Brusso J.L., Clements O.P., Haddon R.C., Itkis M.E., Leitch A.A., Oakley R.T., Reed R.W., Richardson J.F. J. Am. Chem. Soc. 2004, 126:14692.
68. Lekin K., Winter S.M., Downie L.E., Bao X., Tse J.S., Desgreniers S., Secco R.A., Dube P.A., Oakley R.T. J. Am. Chem. Soc. 2010, 132:16212.
69. Alberola A., Collis R.J., Humphrey S.M., Less R.J., Rawson J.M. Inorg. Chem. 2006, 45:1903.
70. Preuss K.E. Dalton Trans. 2007, 2357.
71. Mito M., Kawagoe S., Deguchi H., Takagi S., Fujita W., Awaga K., Kondo R., Kagoshima S. J. Phys. Soc. Jpn. 2009, 78. 124705/1.
72. Hu L., Iwasaki A., Suizu R., Yoshikawa H., Awaga K., Ito H. Chem. Phys. Lett. 2010, 484:177.
73. Iwasaki A., Hu L., Suizu R., Nomura K., Yoshikawa H., Awaga K., Noda Y., Kanai K., Ouchi Y., Seki K., Ito H. Angew. Chem. Int. Ed. 2009, 48:4022.
74. Fujita W., Kikuchi K., Awaga K. Angew. Chem., Int. Ed. 2008, 47:9480.
75. Winter S.M., Cvrkalj K., Robertson C.M., Probert M.R., Dube P.A., Howard J.A.K., Oakley R.T. Chem. Commun. 2009, 7306.
76. Mito M., Komorida Y., Tsuruda H., Tse J.S., Desgreniers S., Ohishi Y., Leitch A.A., Cvrkalj K., Robertson C.M., Oakley R.T. J. Am. Chem. Soc. 2009, 131:16012.
77. Bucholz C.F. Gehlen's Neues J. Chem. 1804, 3:7.
78. Low H.S., Beaudet R.A. J. Am. Chem. Soc. 1976, 98:3849.
79. Burns R.C., Gillespie R.J., Sawyer J.F. Inorg. Chem. 1980, 19:1423.
80. Passmore J., Sutherland G., Taylor P., Whidden T.K., White P.S. Inorg. Chem. 1981, 20:3839.
81. Krossing I., Passmore J. Inorg. Chem. 2004, 43:1000.
82. Steudel R. Top Curr. Chem. 2003, 231:127.
83. Neumüller B., Schmock F., Kirmse R., Voigt A., Diefenbach A., Bickelhaupt F.M., Dehnicke K. Angew. Chem. 2000, 112:4753.
84. Hünig S., Sinzger S.K., Bau R., Metzenthin T., Salbeck J. Chem. Ber. 1993, 126:465.
85. Russell G.A., Law W.C., Zaleta M. J. Am. Chem. Soc. 1985, 107:4175.
86. Musker W.K. Acc. Chem. Res. 1980, 13:200.
87. Aleman C., Brillas E., Davies A.G., Fajari L., Giro D., Julia L., Perez J.J., Rius J. J. Org. Chem. 1993, 58:3091.
88. Gilmore J.R., Mellor J.M. Tetrahedron Lett. 1971, 3977.
89. Guay J., Diaz A., Wu R., Tour J.M. J. Am. Chem. Soc. 1993, 115:1869.
90. Ogawa S., Nakajo S., Muraoka H., Kawai Y., Sato R. J. Sulf. Chem. 2009, 30:293.
91. Dinnocenzo J.P., Banach T.E. J. Am. Chem. Soc. 1986, 108:6063.
92. Asmus K.D. Acc. Chem. Res. 1979, 12:436.
93. Glass R.S. Top Curr. Chem. 1999, 205:1.
94. Nishinaga T., Komatsu K. Org. Biomol. Chem. 2005, 3:561.
95. Smith J.R., Cox P.A., Campbell S.A., Ratcliffe N.M. J. Chem. Soc. Farad. Trans. 1995, 91:2331.
96. Roncali J. Chem. Rev. 1992, 92:711.
97. Tabakovic I., Maki T., Miller L.L., Yu Y. Chem. Commun. 1996, 1911.
98. Wakamiya A., Nishinaga T., Komatsu K. Chem. Commun. 2002, 1192.
99. Nishinaga T., Wakamiya A., Yamazaki D., Komatsu K. J. Am. Chem. Soc. 2004, 126:3163.
100. Graf D.D., Campbell J.P., Miller L.L., Mann K.R. J. Am. Chem. Soc. 1996, 118:5480.
101. Graf D.D., Duan R.G., Campbell J.P., Miller L.L., Mann K.R. J. Am. Chem. Soc. 1997, 119:5888.
102. Yamazaki D., Nishinaga T., Tanino N., Komatsu K. J. Am. Chem. Soc. 2006, 128:14470.
103. Singh R., Singh R.A. Mol. Cryst. Liq. Cryst. Sci. Tech. Sec. C 1997, 8:187.
104. Uchida T., Ito M., Kozawa K. Bull. Chem. Soc. Jpn. 1983, 56:577.
105. Okamoto T., Kuratsu M., Kozaki M., Hirotsu K., Ichimura A., Matsushita T., Okada K. Org. Lett. 2004, 6:3493.
106. Oka H. Org. Lett. 2010, 12:448.
107. Sun D., Rosokha S.V., Kochi J.K. J. Am. Chem. Soc. 2004, 126:1388.
108. Oka H. J. Mater. Chem. 2008, 18:1927.
109. Sato Y., Kinoshita M., Sano M., Akamatu H. Bull. Chem. Soc. Jpn. 1967, 40:2539.
110. Sato Y., Kinoshita M., Sano M., Akamatu H. Bull. Chem. Soc. Jpn. 1969, 42:548.
111. Lida Y. Bull. Chem. Soc. Jpn. 1971, 44:663.
112. Ferraris J., Cowan D., Walatka W., Perlstein J. J. Am. Chem. Soc. 1973, 95:948.
113. Williams J.M., Ferraro J.R., Thorn R.J., Carlson K.D., Geiser U., Wang H.H., Kini A.M., Whangbo M.H. Organic Superconductors. Synthesis, Structure, Properties and Theory 1992, Prentice Hall, Englewood Cliffs, NJ. R.N. Grimes (Ed.).
114. Coms R. Chemistry and Physics of One Dimensional Metals, vol. 25 1977, 315. Plenum, NY, NATO Adv Study Institutes Series, B-Physics. H.J. Keller (Ed.).
115. Selected examples:.
116. Lu W., Zhu Q.-Y., Dai J., Zhang Y., Bian G.-Q., Liu Y., Zhang D.-Q. Cryst. Growth Des. 2007, 7:652.
117. Endres H., Naturforsch Z. B: Chem. Sci. 1986, 41:1437.
118. Endres H. Acta Cryst. C 1987, 43:439.
119. Honda K., Goto M., Kurahashi M., Anzai H., Tokumoto M., Ishiguro T. Bull. Chem. Soc. Jpn. 1988, 61:588.
120. Reinheimer E.W., Zhao H., Dunbar K.R. Synth. Met. 2008, 158:447.
121. Devic T., Avarvari N., Batail P. Chem. Eur. J. 2004, 10:3697.
122. Shibaeva R.P., Rozenberg L.P. Crystallogr. Rep. 1981, 26:1224.
123. Enomoto M., Miyazaki A., Enoki T. Bull. Chem. Soc. Jpn. 2001, 74:459.
124. Kominami T., Matsumoto T., Ueda K., Sugimoto T., Murata K., Shiro M., Fujita H. J. Mater. Chem. 2001, 11:2089.
125. Giffard M., Mabon G., Leclair E., Mercier N., Allain M., Gorgues A., Molinie P., Neilands O., Krief P., Khodorkovsky V. J. Am. Chem. Soc. 2001, 123:3852.
126. Moustarder S.L., Mercier N., Hudhomme P., Gallego-Planas N., Gorgues A., Riou A. Synth. Met. 2002, 130:129.
127. Legros J.-P., Dahan F., Binet L., Fabre J.-M. Synth. Met. 1999, 102:1632.
128. Selected examples:.
129. Matsumoto T., Kamada Y., Sugimoto T., Tada T., Noguchi S., Nakazumi H., Kawakami T., Yamaguchi K., Shiro M. Inorg. Chem. 2003, 42:8638.
130. Liu H.-L., Chou L.-K., Abboud K.A., Ward B.H., Fanucci G.E., Granroth G.E., Canadell E., Meisel M.W., Talham D.R., Tanner D.B. Chem. Mater. 1997, 9:1865.
131. Devic T., Bertran J.N., Domercq B., Canadell E., Avarvari N., Auban-Senzier P., Fourmigue M. New J. Chem. 2001, 25:1418.
132. Brunn K., Endres H., Weiss J. Z. Naturforsch. B: Chem. Sci. 1988, 43:224.
133. Moustarder S.L., Mercier N., Hudhomme P., Gorgues A., Riou A. Synth. Met. 1999, 102:1671.
134. Bock H., Seibel A., Sievert M., Havlas Z. Z. Naturforsch. B: Chem. Sci. 2000, 55:597.
135. Weakley T.J.R. Cryst. Struct. Commun. 1982, 11:681.
136. Hinrichs W., Berges P., Klar G., Naturforsch Z. B:Chem. Sci. 1987, 42:169.
137. Soderholm S., Noreland J., Olovsson G., Olovsson I., Hellberg J., Engman L. Mol. Cryst. Liq. Cryst. 1989, 167:259.
138. Noreland J., Olovsson G., Olovsson I. Acta Cryst. C 1991, 47:2542.
139. Noreland J., Olovsson G., Olovsson I. Synth. Met. 1991, 42:1691.
140. Bock H., Rauschenbach A., Nather C., Kleine M., Havlas Z. Chem. Ber. 1994, 127:2043.
141. Bock H., Rauschenbach A., Nather C., Kleine M., Bats J.W. Phosph. Sulf. Sil. Relat. Elem. 1996, 115:51.
142. Beck J., Bredow T., Tjahjanto R.T., Naturforsch Z. B: Chem. Sci. 2009, 64b:145.
143. Rosokha S.V., Lu J., Rosokha T.Y., Kochi J.K. Acta Cryst. C 2007, 63:o347.
144. de Sorgo M., Wasserman B., Szwarc M. J. Phys. Chem. 1972, 76:3468.
145. Rapta P., Kress L., Hapiot P., Dunsch L. Phys. Chem. Chem. Phys. 2002, 4:4181.
146. Bryce M.R., Lay A.K., Chesney A., Batsanov A.S., Howard J.A.K., Buser U., Gerson F., Merstetter P. J. Chem. Soc. Perkin Trans. 1999, 2:755.
147. Nishinaga T., Wakamiya A., Komatsu K. Tetrahedron Lett. 1999, 40:4375.
148. Block E., Birringer M., DeOrazio R., Fabian J., Glass R.S., Guo C., He C., Lorance E., Qian Q., Schroeder T.B., Shan Z., Thiruvazhi M., Wilson G.S., Zhang X. J. Am. Chem. Soc. 2000, 122:5052.
149. Wakamiya A., Nishinaga T., Komatsu K. J. Am. Chem. Soc. 2002, 124:15038.
150. Shibaeva R.P., Kaminskii V.F., Kushch N.D., Zvarikina A.V., Yagubskii E.B. Dokl. Akad. Nauk SSSR 1980, 251:162.
151. Sekizaki S., Tada C., Yamochia H., Saito G. J. Mater. Chem. 2001, 11:2293.
152. Aso Y., Yui K., Miyoshi T., Otsubo T., Ogura F., Tanaka J. Bull. Chem. Soc. Jpn. 1988, 61:2013.
153. Nigrey P.J., Katz H. J. Appl. Cryst. 1979, 12:255.
154. Banister A.J., Clarke H.G., Rayment I., Shearer H.M.M. Inorg. Nucl. Chem. Lett. 1974, 10:647.
155. Krebs B., Henkel G., Pohl S., Roesky H.W. Chem. Ber. 1980, 113:226.
156. Ayres B., Banister A.J., Coates P.D., Hansford M.I., Rawson J.M., Rickard C.E.F., Hursthouse M.B., Malik K.M.A., Motevalli M. J. Chem. Soc. Dalton Trans. 1992, 3097.
157. Thewalt U., Burger M. Z. Naturforsch. B 1981, 36:293.
158. Roesky H.W., Witt M., Schimkowiak J., Schmidt M., Noltemeyer M., Sheldrick G.M. Angew. Chem 1982, 94:541.
159. Gillespie R.J., Kent J.P., Sawyer J.F. Inorg. Chem. 1981, 20:3784.
160. Gillespie R.J., Ireland P.R., Vekris J.E. Can. J. Chem. 1975, 53:3147.
161. Banister A.J., Clegg W., Hauptman Z.V., Luke A.W., Wait S.T. J. Chem. Soc. Chem. Commun. 1989, 351.
162. Banister A.J., Hansford M.I., Hauptman Z.V., Luke A.W., Wait S.T., Clegg W., Jorgensen K.A. J. Chem. Soc. Dalton Trans. 1990, 2793.
163. Wolmershauser G., Brulet C.R., Street G.B. Inorg. Chem. 1978, 17:3586.
164. Gillespie R.J., Kent J.P., Sawyer J.F. Inorg. Chem. 1981, 20:4053.
165. Awere E.G., Passmore J., White P.S., Klapotke T. J. Chem. Soc. Chem. Commun. 1989, 1415.
166. Haas A., Kasprowski J., Angermund K., Betz P., Krueger C., Tsay Y.H., Werner S. Chem. Ber. 1991, 124:1895.
167. Awere E.G., Brooks W.V.F., Passmore J., White P.S., Sun X., Cameron T.S. J. Chem. Soc. Dalton Trans. 1993, 16:2439.
168. Maaninen A., Konu J., Laitinen R.S., Chivers T., Schatte G., Pietikaeinen J., Ahlgren M. Inorg. Chem. 2001, 40:3539.
169. Feher F., Langer M., Volkert R. Z. Naturforsch. B 1972, 27:1006.
170. Chenard B.L., Harlow R.L., Johnson A.L., Vladuchick S.A. J. Am. Chem. Soc. 1985, 107:3871.
171. Kimura T., Ogawa S., Sato R. Mini-Rev. Org. Chem. 2007, 4:15.
172. Ogawa S., Ohmiya T., Kikuchi T., Kawaguchi A., Saito S., Sai A., Ohyama N., Kawai Y., Niizuma S., Nakajo S., Kimura T., Sato R. J. Organomet. Chem. 2000, 611:136.
173. Nagahora N., Ogawa S., Yoshimura S., Kawai Y., Sato R. Bull. Chem. Soc. Jpn. 2003, 76:1043.
174. Kimura T., Sasaki T., Yamaki H., Suzuki E., Niizuma S. Eur. J. Org. Chem. 2003, 4902.
175. Kimura T., Ito K., Ogawa S., Sato R., Kawai Y. Heteroatom Chem. 2005, 16:111.
176. Kimura T., Ito S., Sasaki T., Ogawa S., Sato R., Kawai Y. Heteroatom Chem. 2008, 19:394.
177. Fanghanel E., Herrmann R., Naarmann H. Tetrahedron 1995, 51:2533.
178. Ogawa S., Nobuta S., Nakayama R., Kawai Y., Niizuma S., Sato R. Chem. Lett. 1996, 757.
179. Cameron T.S., Haddon R.C., Mattar S.M., Parsons S., Passmore J., Ramirez A.P. J. Chem. Soc. Chem. Commun. 1991, 358.
180. Krossing I. Top. Curr. Chem. 2003, 230:135. Synthesis and properties of sulfur homopolyatomic cations have been recently reviewed, see.
181. Cameron T.S., Haddon R.C., Mattar S.M., Parsons S., Passmore J., Ramirez A.P. J. Chem. Soc. Dalton Trans. 1992, 1563.
182. Russell G.A., Tanikaga R., Talaty E.R. J. Am. Chem. Soc. 1971, 94:6125.
183. Bock H., Rittmeyer P., Stein U. Chem. Ber. 1986, 119:3766.
184. Bock H., Hierholzer B., Rittmeyer P. Z. Naturforsch. B 1989, 44:187.
185. Cameron T.S., Haddon R.C., Mattar S.M., Parsons S., Passmore J., Ramirez A.P. Inorg. Chem. 1992, 31:2274.
186. Decken A., Mattar S.M., Passmore J., Shuvaev K.V., Thompson L.K. Inorg. Chem. 2006, 45:3878.
187. Cameron T.S., Decken A., Kowalczyk R.M., McInnes E.J.L., Passmore J., Rawson J.M., Shuvaev K.V., Thompson L.K. J. Chem. Soc. Chem. Commun. 2006, 2277.
188. Boyle P.D., Parsons S., Passmore J., Wood D.J. J. Chem. Soc. Chem. Commun. 1993, 199.
189. Boyle P.D., Parsons S., Passmore J., Wood D.J. J. Chem. Soc. Chem. Commun. 1994, 676.
190. Boyle P.D., Passmore J., Wood D.J. Phosph. Sulf. Sil. 1994, 93/94:227.
191. Enright G.D., Morton J.R., Passmore J., Preston K.F., Thompson R.C., Wood D.J. J. Chem. Soc. Chem. Commun. 1996, 967.
192. Berces A., Enright G.D., Morton J.R., Passmore J., Preston K.F., Thompson R.C., Wood D.J. Phosph. Sulf. Sil. 1997, 124/125:331.
193. Boyle P.D., Cameron T.S., Decken A., Passmore J., Wood D.J. Phosph. Sulf. Sil. 1997, 124/125:549.
194. Berces A., Enright G.D., Mclaurin G.E., Morton J.R., Preston K.F., Passmore J., Wood D.J. Magn. Res. Chem. 1999, 37:353.
195. Cameron T.S., Decken A., Grein F., Knapp C., Passmore J., Rautiainen J.M., Shuvaev K.V., Thompson R.C., Wood D.J. Inorg. Chem. 2010, 49:7861.
196. Decken A., Ebdah M., Kowalczyk R.M., Landee C.P., McInnes E.J.L., Passmore J., Shuvaev K.V., Thompson L.K. Inorg. Chem. 2007, 46:7756.
197. E. Revard, Honors Thesis, University of New Brunswick, 2001.
198. E. Rivard, K.V. Shuvaev, A. Decken, J. Passmore, unpublished results.
199. S4(SbF6)2 and S8(SbF6)2 have not yet been isolated on the solid state and we do not suggest that these species are actually formed.
200. Cameron T.S., Decken A., Fang M., Parsons S., Passmore J., Wood D.J. Chem. Commun. 1999, 1801.
201. D.J. Wood, Ph.D. thesis, University of New Brunswick, 2001.
202. M. Fang, Ph.D. thesis, University of New Brunswick, 2003.
203. Fang M., Passmore J., Decken A. Inorg. Chem. 2005, 44:1672.
204. Makarov Yu.A., Kim S.N., Gritsan N.P., Bagryanskaya Yu.I., Bagryansky V.A., Gatilov Yu.V., Zibarev A.V. Mendeleev Commun. 2005, 15:14.
205. Gleiter R. Angew. Chem. Int. Ed. 1981, 20:444.
206. Nyburg S.C., Faerman C.H. Acta Crystallogr. Sect. B 1985, B41:274.
207. R.M. Kowalczyk, E.J.L. McInnes, D. Collison, Private Communication.
208. Oka H., Terane M., Kiyohara Y., Tanaka H. Polyhedron 2007, 26:1895.
209. Forrest D., Ingold K.U. J. Am. Chem. Soc. 1978, 100:3868.
210. Geiger W.E. J. Phys. Chem. 1973, 77:1862.
211. Fairhurst S.A., Johnson K.M., Sutcliffe L.H., Preston K.F., Banister A.J., Hauptman Z.V., Passmore J. J. Chem. Soc. Dalton Trans. 1986, 1465.
212. Palacio F., Antorrena G., Castro M., Burriel R., Rawson J., Smith J.N.B., Bricklebank N., Novoa J., Ritter C. Phys. Rev. Lett. 1997, 79:2336.
213. Luzon J., Campo J., Palacio F., McIntyre G.J., Goeta A.E., Ressouche E., Pask C.M., Rawson J.M. Physica B 2003, 335:1.
214. Noodleman L., Norman J.G. J. Chem. Phys. 1979, 70:4903.
215. Noodleman L. J. Chem. Phys. 1981, 74:5737.
216. G.P. Antorrena, Ph.D. Thesis, Universidad de Zaragoza, Zaragoza, Spain, 1998.
217. Palacio F. Magnetic Molecular Materials 1991, Kluwer, Dordrecht, (PN NATO ASI, vol. 198).
218. Fujita W., Awaga K., Takahashi M., Takeda M., Yamazaki T. Chem. Phys. Lett. 2002, 362:97.
219. Brusso J.L., Clements O.P., Haddon R.C., Itkis M.E., Leitch A.A., Oakley R.T., Reed R.W., Richardson J.F. J. Am. Chem. Soc. 2004, 126:8256.
220. Beer L., Brusso J.L., Cordes A.W., Haddon R.C., Itkis M.E., Kirschbaum K., MacGregor D.S., Oakley R.T., Pinkerton A.A., Reed R.W. J. Am. Chem. Soc. 2002, 124:9498.
221. Banister A.J. Nat. Phys. Sci. 1972, 237:92.
222. Hund F. Z. Phys. 1925, 33:345.
223. Borden W.T. Encyclopedia of Computational Chemistry 1998, 708. Wiley-Interscience, New York. P. von R. Schleyer (Ed.).
224. Borden W.T., Iwamura H., Berson J.A. Acc. Chem. Res. 1994, 27:109.
225. Jung Y., Head-Gordon M. J. Phys. Chem. A 2003, 107:7475.
226. Jung Y., Head-Gordon M. ChemPhysChem 2003, 4:522.
227. Grützmacher H., Breher F. Angew. Chem. Int. Ed. 2002, 41:4006.
228. Rhee Y.M., Head-Gordon M. J. Am. Chem. Soc. 2008, 130:3878.
229. Genin H., Hoffmann R. Macromolecules 1998, 31:444.
230. Bally T., Borden W.T. Calculations on Open-shell Molecules: A Beginner's Guide. Rev Comput. Chem. 1999, vol. 13:1-97. Wiley-VCH, New York.
231. Bryan C.D., Cordes A.W., Haddon R.C., Hicks R.G., Oakley R.T., Palstra T.T.M., Perel A.J. J. Chem. Soc. Chem. Commun. 1994, 1447.
232. Bryan C.D., Cordes A.W., Goddard J.D., Haddon R.C., Hicks R.G., MacKinnon C.D., Mawhinney R.C., Oakley R.T., Palstra T.T.M., Perel A.J. J. Am. Chem. Soc. 1996, 118:330.
233. Antorrena G., Brownridge S., Cameron T.S., Palacio F., Parsons S., Passmore J., Thompson L.K., Zarlaida F. Can. J. Chem. 2002, 80:1568.
234. Barclay T.M., Beer L., Cordes A.W., Haddon R.C., Itkis M.I., Oakley R.T., Preuss K.E., Reed R.W. J. Am. Chem. Soc. 1999, 121:6657.
235. Ellern A., Bernstein J., Becker J.Y., Zamir S., Shahal L., Cohen S. Chem. Mater. 1994, 6:1378.
236. Oakley R.T., Richardson J.F., Spence R.E.V.H. J. Chem. Soc. Chem. Commun. 1993, 1226.
237. Oakley R.T., Richardson J.F., Spence R.E.V.H. J. Org. Chem. 1994, 59:2997.
238. Chu S.-L., Wai K.-F., Lai T.-F., Sammes M.P. Tetrahedron Lett. 1993, 34:847.
239. Behringer H., Meinetsberger E. Liebigs Ann. Chem. 1981, 1928.
240. Niecke E., Fuchs A., Baumeister F., Nieger M., Schoeller W.W. Angew. Chem. Int. Ed. Engl. 1995, 34:555.
241. Scheschkewitz D., Amii H., Gornitzka H., Schoeller W.W., Bourissou D., Bertrand G. Science 2002, 295:1880.
242. Cui C., Brynda M., Olmstead M.M., Power P.P. J. Am. Chem. Soc. 2004, 126:6510.
243. Cox H., Hitchcock P.B., Lappert M.F., Pierssens L.J.-M. Angew. Chem. Int. Ed. 2004, 43:4500.
244. Cameron T.S., Lemaire M.T., Passmore J., Rawson J.M., Shuvaev K.V., Thompson L.K. Inorg. Chem. 2005, 44:2576.
245. Decken A., Cameron T.S., Passmore J., Rautiainen J.M., Reed R.W., Shuvaev K.V., Thompson L.K. Inorg. Chem. 2007, 46:7436.
246. Brook D.J.R., Fox H.H., Lynch V., Fox M.A. J. Phys. Chem. 1996, 100:2066.
247. Green M.T., McCornick T.A. Inorg. Chem. 1999, 38:3061.
248. Mota F., Miller J.S., Novoa J.J. J. Am. Chem. Soc. 2009, 131:7699.
249. Garcia-Yoldi I., Miller J.S., Novoa J.J. J. Phys. Chem. A 2009, 113:484.
250. Del Sesto E., Miller J.S., Lafuente P., Novoa J.J. Chem. Eur. J. 2002, 8:4894.
251. Miller J.S., Novoa J.J. Acc. Chem. Res. 2007, 40:189.
252. Brooks W.V.F., Cameron T.S., Parsons S., Passmore J., Schriver M.J. Inorg. Chem. 1994, 33:6230.
253. Krossing I., Passmore J. Inorg. Chem. 1999, 38:5203.
254. Cameron T.S., Dionne I., Jenkins H.D.B., Parsons S., Passmore J., Rowbottom H.K. Inorg. Chem. 2000, 39:2042.
255. Cameron T.S., Deeth R.J., Dionne I., Du H., Jenkins H.D.B., Krossing I., Passmore J., Roobottom H.K. Inorg. Chem. 2000, 39:5614.
256. Awere E.G., Burford N., Mailer C., Passmore J., Schriver M.J., White P.S., Banister A.J., Oberhammer H., Sutcliffe L.H. J. Chem. Soc. Chem. Commun. 1987, 66.
257. Tuononen H.M., Suontamo R., Valkonen J., Laitinen R.S. J. Phys. Chem. A 2004, 5670.
258. Garcia-Yoldi I., Miller J.S., Novoa J.J. Phys. Chem. Chem. Phys. 2008, 10:4106.
259. Garcia-Yoldi I., Miller J.S., Novoa J.J. Theor. Chem. Acc. 2009, 123:137.
260. Gillespie R.J., Passmore J. Acc. Chem. Res. 1971, 4:413.
261. Brownridge S., Krossing I., Passmore J., Jenkins H.D.B., Roobottom H. Coord. Chem. Rev. 2000, 197:397.
262. Brownridge S., Cameron T.S., Du H., Knapp C., Koppe R., Passmore J., Rautiainen J.M., Schnockel H. Inorg. Chem. 2005, 44:1660.
263. Nandana W.A.S., Passmore J., White P.S., Wong C.-M. J. Chem. Soc. Chem. Commun. 1982, 1098.
264. Nandana W.A.S., Passmore J., White P.S., Wong C.-M. Inorg. Chem. 1990, 29:3529.
265. Drews T., Koch W., Seppelt K. J. Am. Chem. Soc. 1999, 121:4379.
266. Arulsamy N., Bohle D.S., Imonigie J.A., Sagan E.S. Inorg. Chem. 1999, 38:2716.
267. Leitch A.A., Yu X., Robertson C.M., Secco R.A., Tse J.S., Oakley R.T. Inorg. Chem. 2009, 48:9874.
268. Beer L., Brusso J.L., Haddon R.C., Itkis M.E., Leitch A.A., Oakley R.T., Reed R.W., Richardson J.F. Chem. Commun. 2005, 1543.
269. Beer L., Brusso J.L., Haddon R.C., Itkis M.E., Kleinke H., Leitch A.A., Oakley R.T., Reed R.W., Richardson J.F., Secco R.A., Yu X. J. Am. Chem. Soc. 2005, 127:18159.
270. Beer L., Reed R.W., Robertson C.M., Oakley R.T., Tham F.S., Haddon R.C. Org. Lett. 2008, 10:3121.
271. Leitch A.A., McKenzie C.E., Oakley R.T., Reed R.W., Richardson J.F., Sawyera L.D. Chem. Commun. 2006, 1088.
272. Zhang Z., Liable-Sands L.M., Rheingold A.L., Del Sesto R.E., Gordon D.C., Burkhart B.M., Miller J.S. J. Chem. Soc. Chem. Commun. 1998, 1385.
273. Harms R.H., Keller H.J., Nöthe D., Werner M., Grundel D., Sixl H., Soos Z.G., Metzger R.M. Mol. Cryst. Liq. Cryst. 1981, 65:179.
274. Hoffman S.K., Corvan P.J., Singh P., Sethuklekshmi C.N., Metzer R.M., Hatfield W.E. J. Am. Chem. Soc. 1983, 105:4608.
275. Zhao H., Heintz R.A., Dunbar K.R., Rogers R.D. J. Am. Chem. Soc. 1996, 118:12844.
276. Miller J.S., O'Hare D.M., Chakraborty A., Epstein A.J. J. Am. Chem. Soc. 1989, 111:7853.
277. Bock H., Ruppert K., Fenske D., Goesmann H., Anorg Z. Allg. Chem. 1991, 595:275.
278. Reid D.H. Tetrahedron 1958, 3:339.
279. Sogo P.B., Nakazaki M., Calvin M. J. Chem. Phys. 1957, 26:1343.
280. Paskovich D.H., Reddoch A.H. J. Am. Chem. Soc. 1972, 94:6938.
281. Gillespie R.J., Passmore J., Ummat P.K., Vaidya O.C. Inorg. Chem. 1971, 10:1327.
282. Less R.J., Rawson J.M., Jones M. Polyhedron 2001, 20:523.
283. Goto K., Kubo T., Yamamoto K., Nakasuji K., Sato K., Shiomi D., Takui T., Kubota M., Kobayashi T., Yakushi K., Ouyang J. J. Am. Chem. Soc. 1999, 121:1619.
284. Morita Y., Suzuki S., Fukui K., Nakazawa S., Kitagawa H., Kishida H., Okamoto H., Naito A., Sekine A., Ohashi Y., Shiro M., Sasaki K., Shiomi D., Sato K., Takui T., Nakasuji K. Nat. Mater. 2008, 7:48.
285. Morita Y., Aoki T., Fukui K., Nakazawa S., Tamaki K., Suzuki S., Fuyuhiro A., Yamamoto K., Sato K., Shiomi D., Naito A., Takui T., Nakasuji K. Angew. Chem. Int. Ed. 2002, 41:1793.
286. Guirauden A., Johannsen I., Batail P., Coulon C. Inorg. Chem. 1993, 32:2446.
287. Reefman D., Cornelissen J.P., de Graaff R.A.G., Haasnoot J.G., Reedijk J. Inorg. Chem. 1991, 30:4928.
288. Metzger R.M., Heimer N.E., Gundel D., Sixl H., Harms R., Keller H.J., Nöthe D., Wehe D. J. Chem. Phys. 1982, 77:6203.
289. Hynes R.C., Krusic P.J., Preston K.F., Springs J.J., Williams A.J., Miller J.S. J. Am. Chem. Soc. 1995, 117:2547.
290. Kochi J.K., Rathore R., Magueres P.L. J. Org. Chem. 2000, 65:6826.
291. Rosokha S.V., Zhang J., Lu J., Kochi J.K. J. Org. Chem. 2010, 23:395.
292. Novoa J.J., Stephens P.W., Weerasekare M., Shum W.W., Miller J.S. J. Am. Chem. Soc. 2009, 131:9070.
293. Rosokha S.V., Lu J., Han B., Kochi J.K. New J. Chem. 2009, 33:545.
294. Shuvaev K.V., Decken A., Grein F., Abedin T.S.M., Thompson L.K., Passmore J. Dalton Trans. 2008, 4029.