1,2-Dithiin annelated with bicyclo[2.2.2]octene Frameworks. One-electron and two-electron oxidations and formation of a novel 2,3,5,6-tetrathiabicyclo[2.2.2]oct-7-ene Radical cation with remarkable stability owing to a strong transannular interaction

Journal of the American Chemical Society

Volumn 124, Issue 50, 2002, Pages 15038-15050

  Wakamiya, Atsushi ^a   Nishinaga, Tohru ^a   Komatsu, Koichi ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

SPIN DISTRIBUTION;

ABSORPTION; CONCENTRATION (PROCESS); CYCLIC VOLTAMMETRY; DIMERS; OXIDATION; POSITIVE IONS; SPECTROSCOPY; SULFUR;

SYNTHESIS (CHEMICAL);

2,3,5,6 TETRATHIABICYCLO[2.2.2]OCT 7 ENE; ALKENE DERIVATIVE; ANTIMONY; BICYCLO COMPOUND; CARBOXYL GROUP; CATION; DITHIOL DERIVATIVE; FLUORIDE; SULFUR; UNCLASSIFIED DRUG;

ABSORPTION; ARTICLE; CALCULATION; CHEMICAL BOND; ELECTRON; ELECTRON SPIN RESONANCE; MOLECULAR INTERACTION; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE; OXIDATION; REACTION ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

BICYCLO COMPOUNDS; BICYCLO COMPOUNDS, HETEROCYCLIC; CATIONS; CYCLOHEXANES; CYCLOHEXENES; CYCLOOCTANES; DISULFIDES; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; MODELS, MOLECULAR;

EID: 0037132623     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja028297j     Document Type: Article

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