Copper-catalyzed oxaziridine-mediated oxidation of C-H bonds

Journal of Organic Chemistry

Volumn 77, Issue 16, 2012, Pages 7005-7022

  Motiwala, Hashim F ^a   Gülgeze, Belgin ^a   Aubé, Jeffrey ^a  

^a UNIVERSITY OF KANSAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALLYLIC RADICALS; BENZYLIC; C-H BOND; CHEMOSELECTIVE OXIDATION; COPPER-CATALYZED REACTIONS; HYDROGEN ATOM ABSTRACTION; OXAZIRIDINES; RADICAL ANIONS; SINGLE ELECTRON TRANSFER;

CATALYSIS; CATALYST REGENERATION; COPPER; ELECTRON TRANSITIONS; HYDROGEN; OXIDATION;

FREE RADICAL REACTIONS;

(2R,3R,1'S) 3 (5 METHYLHEX 4'' EN 1'' YL) 3 PHENYL 2 (1' PHENYLETHYL) 1,2 OXAZIRIDINE; (2R,3R,1'S) 3 (PENT 4'' EN 1'' YL) 3 PHENYL 2 (1' PHENYLETHYL) 1,2 OXAZIRIDINE; (2R,3S) 2 BENZHYDRYL 3 (5 METHYLHEX 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2R,3S) 2 BENZHYDRYL 3 (PENT 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2R,3S) 2 BENZYL 3 (PENT 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2R,3S) 2 CYCLOHEXYL 3 (3,4 DIMETHOXYPHENYL) 3 (PENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2R,3S) 2 CYCLOHEXYL 3 (4 FLUOROPHENYL) 3 (PENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2R,3S) 2 CYCLOHEXYL 3 (5 METHYLHEX 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2R,3S) 2 CYCLOHEXYL 3 (FURAN 2 YL) 3 (PENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2R,3S) 2 CYCLOHEXYL 3 (NAPHTHALEN 2 YL) 3 (PENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2R,3S) 2 CYCLOHEXYL 3 (PENT 4' EN 1' YL) 3 (4 TOLYL) 1,2 OXAZIRIDINE; (2R,3S) 2 CYCLOHEXYL 3 (PENT 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2R,3S,1'S) 3 (5 METHYLHEX 4'' EN 1'' YL) 3 PHENYL 2 (1' PHENYLETHYL) 1,2 OXAZIRIDINE; (2R,3S,1'S) 3 (PENT 4'' EN 1'' YL) 3 PHENYL 2 (1' PHENYLETHYL) 1,2 OXAZIRIDINE; (2R,3S,E) 2 CYCLOHEXYL 3 PHENYL 3 (5' PHENYLPENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2S,3R,1'S) 3 (PENT 4'' EN 1'' YL) 3 PHENYL 2 (1' PHENYLETHYL) 1,2 OXAZIRIDINE; (2S,3S) 2 BENZHYDRYL 3 (PENT 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2S,3S) 2 BENZYL 3 (PENT 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2S,3S) 2 CYCLOHEXYL 3 (3,4 DIMETHOXYPHENYL) 3 (PENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2S,3S) 2 CYCLOHEXYL 3 (4 FLUOROPHENYL) 3 (PENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2S,3S) 2 CYCLOHEXYL 3 (5 METHYLHEX 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2S,3S) 2 CYCLOHEXYL 3 (NAPHTHALEN 2 YL) 3 (PENT 4' EN 1' YL) 1,2 OXAZIRIDINE; (2S,3S) 2 CYCLOHEXYL 3 (PENT 4' EN 1' YL) 3 (4 TOLYL) 1,2 OXAZIRIDINE; (2S,3S) 2 CYCLOHEXYL 3 (PENT 4' EN 1' YL) 3 PHENYL 1,2 OXAZIRIDINE; (2S,3S,E) 2 CYCLOHEXYL 3 PHENYL 3 (5' PHENYLPENT 4' EN 1' YL) 1,2 OXAZIRIDINE; ALLYL COMPOUND; BENZILIC ACID; COPPER; HYDROGEN; OXAZIRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ALLYLIC REARRANGEMENT; ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; HYDROGEN BOND; OXIDATION;

AZIRIDINES; CARBON; CATALYSIS; COPPER; CYCLIC N-OXIDES; ELECTRON TRANSPORT; ELECTRONS; HYDROGEN; KINETICS; MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION-REDUCTION; SPIN TRAPPING; STEREOISOMERISM;

EID: 84865276096     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo3012336     Document Type: Article

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