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Jacobsen, E. N.; Pfaltz, A.; Yamamoto, H., Eds.; Springer-Verlag: Berlin
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Recent reviews: (a) Yanagisawa, A. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N.; Pfaltz, A.; Yamamoto, H., Eds.; Springer-Verlag: Berlin, 1999; Vol. II, pp. 965-979; (b) Denmark, S. E.; Almstead, N. G. In Modern Carbonyl Chemistry; Otera, J., Ed.; Wiley-VCH: Weiheim, 2000; pp. 299-401.
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Recent reviews: (a) Yanagisawa, A. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N.; Pfaltz, A.; Yamamoto, H., Eds.; Springer-Verlag: Berlin, 1999; Vol. II, pp. 965-979; (b) Denmark, S. E.; Almstead, N. G. In Modern Carbonyl Chemistry; Otera, J., Ed.; Wiley-VCH: Weiheim, 2000; pp. 299-401.
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2 for 48 h, and then careful distillation (10 mmHg, 47-49°C, 70∼80% yield), see: Pelter, A.; Smith, K.; Brown, H. C. Borane Reagents; Academic Press: New York, 1988, p. 436.
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Pelter, A.1
Smith, K.2
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0037016467
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Yu C.-M., Lee J.-Y., So B., Hong J. Angew. Chem., Int. Ed. 41:2002;161-163.
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Yu, C.-M.1
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85031161678
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note
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3).
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20
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85031146852
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note
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Compound 12a was reduced by hydrazine hydrate in the presence of KOH to the corresponding (+)-(4R)-7-phenyl-hept-1-2n-4-ol in 41% yield. This alcohol has not only the same specific rotation sign but also identical NMR spectra of (+)-MTPA ester derivatives as compared with synthetic alcohol prepared by allyltributylstannane with 4-phenylbutanal in the presence of (S)-BINOL-Ti(VI) as described in Ref. 4a.
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