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Volumn 48, Issue 31, 2009, Pages 5720-5723

Stereospecific C-H oxidation with H2O2 catalyzed by a chemically robust site-isolated iron catalyst

Author keywords

Catalyst design; Homogeneous catalysis; Iron; Liydrogen peroxide; Oxidation

Indexed keywords

CATALYSIS; IRON; IRON COMPOUNDS; OXIDATION;

EID: 70349789516     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200901865     Document Type: Article
Times cited : (237)

References (49)
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    • CCDC 726566 (3) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
    • CCDC 726566 (3) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
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    • Under analogous conditions, 1,4, and 6 afforded 15 % (A/K = 0.22), 3% (A/K = 2), and 13% (A/K = 0.44) yields respectively.
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    • A third addition resulted in lower yields, presumably because of product overoxidation
    • A third addition resulted in lower yields, presumably because of product overoxidation.
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    • For a recent mechanistic study of the effect of the acetic acid in epoxidation reactions catalyzed by related iron complexes, see: R. Mas-Ballesté, L. Que, Jr., J. Am. Chem. Soc. 2007, 129, 15964-15972.
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    • 6, 3, and 6 can be found as Figure S4 in the Supporting Information.
    • 6, 3, and 6 can be found as Figure S4 in the Supporting Information.
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    • Deactivation of 2 via formation of oligomeric species has been recently proposed; N. A. Vermeulen, M. S. Chen, M. C. White, Tetrahedron 2009, 65, 3078-3084.
    • Deactivation of 2 via formation of oligomeric species has been recently proposed; N. A. Vermeulen, M. S. Chen, M. C. White, Tetrahedron 2009, 65, 3078-3084.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.