Asymmetric epoxidations with H 2O 2 on Fe and Mn aminopyridine catalysts: Probing the nature of active species by combined electron paramagnetic resonance and enantioselectivity study

ACS Catalysis

Volumn 2, Issue 6, 2012, Pages 1196-1202

  Lyakin, Oleg Y ^a   Ottenbacher, Roman V ^b   Bryliakov, Konstantin P ^a   Talsi, Evgenii P ^a  

^a BORESKOV INSTITUTE OF CATALYSIS   (Russian Federation)

^b NOVOSIBIRSK STATE UNIVERSITY   (Russian Federation)

Author keywords

asymmetric catalysis; epoxidation; hydrogen peroxide; intermediate; iron; manganese

Indexed keywords

ACTIVE SPECIES; AMINOPYRIDINES; ASYMMETRIC CATALYSIS; ASYMMETRIC EPOXIDATION; ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY; ENANTIOMERIC EXCESS; HIGH ENANTIOSELECTIVITY; INTERMEDIATE; MANGANESE COMPLEXES; TURNOVER NUMBER;

CARBOXYLIC ACIDS; ELECTRON RESONANCE; ELECTRON SPIN RESONANCE SPECTROSCOPY; EPOXIDATION; HYDROGEN PEROXIDE; IONIZATION OF GASES; IRON; IRON COMPOUNDS; MANGANESE; OLEFINS; PARAMAGNETIC RESONANCE; PARAMAGNETISM;

ENANTIOSELECTIVITY;

EID: 84861824747     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/cs300205n     Document Type: Article

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