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Volumn 351, Issue 3, 2009, Pages 348-352

A broad substrate-scope method for fast, efficient and selective hydrogen peroxide-epoxidation

Author keywords

Catalysis; Chemoselectivity; Epoxidation; Hydrogen peroxide; Manganese

Indexed keywords


EID: 60849121098     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/adsc.200800650     Document Type: Article
Times cited : (110)

References (43)
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    • Selected Mn based systems; a R. Hage et al., Nature 1994, 369, 637;
    • Selected Mn based systems; a) R. Hage et al., Nature 1994, 369, 637;
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    • Selected Fe-based systems a K. Schröder, X. Tong, B. Bitterlich, M. K. Tse, F. G. Gelalcha, A. Brückner, M. Beller, Tetrahedron Lett. 2007, 48, 6339;
    • Selected Fe-based systems a) K. Schröder, X. Tong, B. Bitterlich, M. K. Tse, F. G. Gelalcha, A. Brückner, M. Beller, Tetrahedron Lett. 2007, 48, 6339;
  • 24
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    • I. Garcia-Bosch, A. Company, X. Fontrodona, X. Ribas, M. Costas, Org. Lett. 2008, 10, 2095.
    • I. Garcia-Bosch, A. Company, X. Fontrodona, X. Ribas, M. Costas, Org. Lett. 2008, 10, 2095.
  • 26
    • 60849128427 scopus 로고    scopus 로고
    • Blank experiments with cis-cyclooctene, 1-octene and styrene confirmed that no epoxidation occurs in the absence of the manganese catalyst
    • Blank experiments with cis-cyclooctene, 1-octene and styrene confirmed that no epoxidation occurs in the absence of the manganese catalyst.
  • 27
    • 0033527598 scopus 로고    scopus 로고
    • For examples of beneficial effects of carboxylic acids in Mn-catalyzed oxidation reactions see, a A. Berkessel, C. A. Sklorz Tetrahedron Lett. 1999, 40, 7965;
    • For examples of beneficial effects of carboxylic acids in Mn-catalyzed oxidation reactions see, a) A. Berkessel, C. A. Sklorz Tetrahedron Lett. 1999, 40, 7965;
  • 29
    • 60849118858 scopus 로고    scopus 로고
    • For systems exhibiting both epoxidation and cis-dihydroxylation see refs.[4c,d
    • [4c,d]
  • 35
    • 60849088462 scopus 로고    scopus 로고
    • L. Gómez, I. Garcia-Bosch, A. Company, X. Sala, X. Fontrodona, M. Ribas, M. Costas, Dalton Trans. 2007, 5539;
    • f) L. Gómez, I. Garcia-Bosch, A. Company, X. Sala, X. Fontrodona, M. Ribas, M. Costas, Dalton Trans. 2007, 5539;
  • 39
    • 60849105286 scopus 로고    scopus 로고
    • 2 and 2,2′-bipyridine in acetonitrile.
    • 2 and 2,2′-bipyridine in acetonitrile.
  • 40
    • 60849085105 scopus 로고    scopus 로고
    • Under analogous conditions, the epoxidation of 1-octene and styrene catalyzed by 3 affords the corresponding epoxides in respective 81% yield (81% conversion, 36% yield 36% conversion
    • Under analogous conditions, the epoxidation of 1-octene and styrene catalyzed by 3 affords the corresponding epoxides in respective 81% yield (81% conversion), 36% yield (36% conversion).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.