메뉴 건너뛰기




Volumn 125, Issue 18, 2003, Pages 5250-5251

Efficient epoxidation of electron-deficient olefins with a cationic manganese complex

Author keywords

[No Author keywords available]

Indexed keywords

1 HEPTENE; 1 METHYLCYCLOHEXENE; 2 CYCLOHEXENONE; 2 HEPTENE; 2 METHYL 1 PENTENE; ALKENE DERIVATIVE; ALLYL ACETATE; BETA METHYLSTYRENE; CARVONE; CYCLOHEXENE; CYCLOOCTENE; EPOXIDE; LEWIS ACID; MANGANESE DERIVATIVE; METAL COMPLEX; METHACRYLIC ACID METHYL ESTER; OXIDIZING AGENT; PERACETIC ACID; SORBIC ACID ETHYL ESTER; UNCLASSIFIED DRUG; VINYL CYCLOHEXANE;

EID: 0037955666     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029962r     Document Type: Article
Times cited : (243)

References (34)
  • 11
    • 0037921128 scopus 로고    scopus 로고
    • note
    • mep=N, N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethane-1,2-diamine. R,R-mcp = N,N′-dimethyI-N,N′ -bis(2-pyridylmethyl)cyclohexane-1R,2R-di-amine.
  • 16
    • 0038597412 scopus 로고    scopus 로고
    • note
    • 3, 3401 reflections (4° < 20 < 43.94°), R(Rw) = 0.036 (0.095).
  • 27
    • 0038258661 scopus 로고    scopus 로고
    • note
    • 2 free.
  • 28
    • 0037921123 scopus 로고    scopus 로고
    • note
    • 2 and HOAc using 1% sulfuric acid catalyst.
  • 29
    • 0037921124 scopus 로고    scopus 로고
    • note
    • 2-. CDTA = trans-cyclobexyl-1,2-diamine tetraacetic acid.
  • 30
    • 0037921127 scopus 로고    scopus 로고
    • note
    • 2 shows no reactivity under these conditions.
  • 31
    • 0037921125 scopus 로고    scopus 로고
    • note
    • This system does not exclusively provide the epoxide product for sensitive olefins such as styrene, ethyl acrylate, or α-pinene.
  • 32
    • 0037921126 scopus 로고    scopus 로고
    • note
    • 2 salt and R,R-mcp. In addition, these reactions can be run in an identical manner when glacial acetic acid is used as the solvent.
  • 34
    • 0038258718 scopus 로고    scopus 로고
    • note
    • 2+ have a similar scope of reactivity but require higher catalyst loadings. P. Hung, unpublished results.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.