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Angewandte Chemie - International Edition

Volumn 47, Issue 10, 2008, Pages 1887-1889

Iron-catalyzed asymmetric olefin cis-dihydroxylation with 97% enantiomeric excess

(3) Suzuki, Ken b Oldenburg, Paul D a Que Jr , Lawrence a

a University of Minnesota (United States)

b TAKASAGO INTERNATIONAL CORPORATION (Japan)

Author keywords

Asymmetric catalysis; Dihydroxylation; Iron; N ligands; Oxidation

Indexed keywords

ASYMMETRIC CATALYSIS; DIHYDROXYLATION; IRON; N LIGANDS; OXIDATION;

OLEFINS;

ALKENE; FERROUS ION; HYDROGEN PEROXIDE; LIGAND;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; HYDROXYLATION; OXIDATION REDUCTION REACTION; STEREOISOMERISM; SYNTHESIS;

ALKENES; CATALYSIS; FERROUS COMPOUNDS; HYDROGEN PEROXIDE; HYDROXYLATION; LIGANDS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; STEREOISOMERISM;

EID: 41949125347 PISSN: 14337851 EISSN: None Source Type: Journal
DOI: 10.1002/anie.200705061 Document Type: Article

Times cited : (202)

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- Single-crystal structure and refinement data for 1: C 22H26F6FeN4O6S 2, Mw=676.44, monoclinic, space group P21, a=9.184(1, b=28.648(3, c=10.614(1) Å, β=90.950(2)°, V= 2792.1(5) Å3, Z=4, ρcalcd=1.609 Mgm-3, MoKα radiation (λ= 0.71073 Å, μ=0.774 mm-1, T=173(2) K. A total of 12444 (Rint=0.0435) independent reflections with 2θ<27.50° were collected. The resulting parameters were refined to converge at R1=0.0438 (I>2θ) for 739 parameters on 12444 independent reflections wR 2=0.0971, Max./min. residual electron density 0.626/-0.487 eÅ-3; GOF=1.026. Single-crystal structure and refinement data for 2: C33H38Cl
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