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Volumn 14, Issue 19, 2008, Pages 5727-5731

A novel platform for modeling oxidative catalysis in non-heme iron oxygenases with unprecedented efficiency

Author keywords

Bioinorganic chemistry; Enzyme catalysis; Model compounds; Non heme oxygenases; Oxidation

Indexed keywords

HEMOGLOBIN; HYDROCARBONS; PARAFFINS; PORPHYRINS;

EID: 53849111893     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200800724     Document Type: Article
Times cited : (132)

References (37)
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    • Crystal data for 1·CF3SO3: C 20H32F6FeN4O6S 2, monoclinic. P21/c, a, 8.994(3) b, 20.446(6, c, 15.012(5) Å, β, 91.735(5)°. V, 2759.4 (14) Å3, Z, 4, ρcalcd, 1.585 gcm -3. μ, 0.781 mm-1, T= 100(2) K, crystal size, 0.1 × 0.05 × 0.01 mm. θ range, 1.99-28.15°, unique reflections, 6626. parameters, 356, GoF, 1.120, R1 [I>2σ (I, 0.0650, wR2 [1 > 2σ(1, 0.1302. Crystal data for[3·CH3CN]PF6: C18H 30F12FeN6P2, monoclinic, P21m. a, 7.9099(4, b, 9.8035(5, c, 16.6584(9) Å, β, 90.9770(10)°, V, 1291.58(12) Å3. Z=2, ρcalcd= 1.739 g cm
    • 3) contain the supplementary crystallography data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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    • 2 addition; longer reaction times did not result in significant differences in reactions efficiencies.
    • 2 addition; longer reaction times did not result in significant differences in reactions efficiencies.
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    • 2/cyclohexane/ cyclohexanol 1:100:972:28) that yielded a A/K = 1.75. a value significantly lower than using only 1000 equiv cyclohexane (A/K = 2.6).
    • 2/cyclohexane/ cyclohexanol 1:100:972:28) that yielded a A/K = 1.75. a value significantly lower than using only 1000 equiv cyclohexane (A/K = 2.6).
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    • 2(BPMEN)] as the catalyst afforded a 47% yield with a D/E ratio of 0.23.
    • 2(BPMEN)] as the catalyst afforded a 47% yield with a D/E ratio of 0.23.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.