On the mechanism of the palladium-catalyzed β-arylation of ester enolates

Chemistry - A European Journal

Volumn 18, Issue 7, 2012, Pages 1932-1944

  Larini, Paolo ^a   Kefalidis, Christos E ^b   Jazzar, Rodolphe ^a   Renaudat, Alice ^a   Clot, Eric ^b   Baudoin, Olivier ^a  

^a UNIVERSITÉ LYON 1   (France)

^b UNIVERSITÉ DE MONTPELLIER   (France)

Author keywords

arylation; density functional calculations; isomerization; palladium; reaction mechanisms

Indexed keywords

ARYL BROMIDES; ARYLATION REACTIONS; ARYLATIONS; DENSITY-FUNCTIONAL CALCULATIONS; DFT CALCULATION; ELECTRON WITHDRAWING GROUP; ELECTRON-WITHDRAWING SUBSTITUENTS; ELECTRONIC FACTORS; ENOLATES; METAL CENTERS; RATE-LIMITING STEPS; REACTION MECHANISM; REDUCTIVE ELIMINATION; STABILIZING INTERACTIONS; SUBSTITUTION PATTERNS; TRANSITION STATE;

AROMATIC COMPOUNDS; BROMINE COMPOUNDS; CATALYSIS; DENSITY FUNCTIONAL THEORY; DEUTERIUM; ESTERIFICATION; ESTERS; ISOMERIZATION; ISOMERS; KINETICS; LIGANDS; METAL HALIDES; OLEFINS; PALLADIUM;

REACTION KINETICS;

EID: 84856690416     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201103153     Document Type: Article

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