Measurement of the barrier to β-hydride elimination in a β-agostic palladium-ethyl complex: A model for the energetics of chain-walking in (α-diimine)PdR+ olefin polymerization catalysts

Organometallics

Volumn 20, Issue 19, 2001, Pages 3975-3982

  Shultz, Leigh Huff ^a   Brookhart, Maurice ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHAIN WALKING; DIETHYL COMPLEX; PROTONATION; REGIOCHEMISTRY;

CATALYSTS; HYDRIDES; MICROSTRUCTURE; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PALLADIUM COMPOUNDS; POLYMERIZATION; POLYOLEFINS; POSITIVE IONS; SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 0035904257     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010197j     Document Type: Article

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