Linking conformational flexibility and kinetics: Catalytic 1,4-type friedel-crafts reactions of phenols utilizing 1,3-diamine-tethered guanidine/bisthiourea organocatalysts

Chemistry - An Asian Journal

Volumn 6, Issue 9, 2011, Pages 2463-2470

  Sohtome, Yoshihiro ^a,b   Shin, Bongki ^a   Horitsugi, Natsuko ^a   Noguchi, Keiichi ^a   Nagasawa, Kazuo ^a  

^a TOKYO UNIVERSITY OF AGRICULTURE AND TECHNOLOGY   (Japan)

^b RIKEN   (Japan)

Author keywords

asymmetric synthesis; entropy; Friedel Crafts reaction; organocatalysis; phenols

Indexed keywords

ACTIVATION ENTHALPIES; ACTIVATION ENTROPIES; ASYMMETRIC SYNTHESIS; CONFORMATIONAL FLEXIBILITY; COOPERATIVE MECHANISMS; ENANTIOSELECTIVE; EYRING PLOT; KINETIC ANALYSIS; ORGANOCATALYSIS; ORGANOCATALYSTS; STRUCTURAL MOTIFS;

ENTROPY; FRIEDEL-CRAFTS REACTION; REACTION KINETICS; SYNTHESIS (CHEMICAL); THIOUREAS; UREA;

PHENOLS;

DIAMINE; GUANIDINE; PHENOL DERIVATIVE; THIOUREA;

ARTICLE; CATALYSIS; CHEMISTRY; ENTROPY; KINETICS; STEREOISOMERISM;

CATALYSIS; DIAMINES; ENTROPY; GUANIDINE; KINETICS; PHENOLS; STEREOISOMERISM; THIOUREA;

EID: 80051724270     PISSN: 18614728     EISSN: 1861471X     Source Type: Journal    
DOI: 10.1002/asia.201100363     Document Type: Article

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