A synthetic host-guest system achieves avidin-biotin affinity by overcoming enthalpy - Entropy compensation

Proceedings of the National Academy of Sciences of the United States of America

Volumn 104, Issue 52, 2007, Pages 20737-20742

  Rekharsky, Mikhail V ^a   Mori, Tadashi ^a   Yang, Cheng ^a   Young, Ho Ko ^b   Selvapalam, N ^b   Kim, Hyunuk ^b   Sobransingh, David ^c   Kaifer, Angel E ^c   Liu, Simin ^d   Isaacs, Lyle ^d   Chen, Wei ^e,f   Moghaddam, Sarvin ^e   Gilson, Michael K ^e,f   Kim, Oon ^b   Inoue, Yoshihisa ^a  

^a OSAKA UNIVERSITY   (Japan)

^b Pohang University of Science and Technology (POSTECH)   (South Korea)

^c Department of Biology   (United States)

^d Bldg 142   (United States)

^e UNIVERSITY OF MARYLAND BIOTECHNOLOGY INSTITUTE   (United States)

^f VeraChem LLC   (United States)

Author keywords

Cucurbituril; Entropy control; Ferrocene derivatives; Host guest complexation; Thermodynamics

Indexed keywords

AVIDIN; BIOTIN; BIS(TRIMETHYLAMMONIOMETHYL)FERROCENE; CUCURBITURIL; FERROCENE DERIVATIVE; MACROCYCLIC COMPOUND; PLANT EXTRACT; UNCLASSIFIED DRUG;

AQUEOUS SOLUTION; ARTICLE; BINDING AFFINITY; COMPLEX FORMATION; ENERGY TRANSFER; ENTHALPY; ENTROPY; MOLECULAR RECOGNITION; PRIORITY JOURNAL; SOLVATION; SQUASH; THERMODYNAMICS;

AVIDIN; BIOTIN; BIOTINYLATION; BRIDGED COMPOUNDS; CALORIMETRY; CHEMISTRY; CRYSTALLOGRAPHY, X-RAY; ENTROPY; HYDROGEN BONDING; IMIDAZOLES; KINETICS; MODELS, MOLECULAR; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; STREPTAVIDIN; THERMODYNAMICS;

EID: 38049144318     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.0706407105     Document Type: Article

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