Temperature-effected tuning of enantioselectivity in asymmetric catalysis

Tetrahedron Letters

Volumn 39, Issue 20, 1998, Pages 3201-3204

  Otera, Junzo ^a   Sakamoto, Katsumasa ^a   Tsukamoto, Takao ^a   Orita, Akihiro ^a  

^a OKAYAMA UNIVERSITY OF SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBAMIC ACID; ORGANIC COMPOUND;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CHIRALITY; ENANTIOMER; REACTION ANALYSIS; SYNTHESIS;

EID: 0032516387     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4039(98)00459-6     Document Type: Article

References (32)

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26. 13
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29. 14. The %ee's of 4 were determined as their acetates 6 on chiral HPLC (Daicel Chiralpak AD). The absolute configuration of 4a was determined by comparison of its acetate 6a with authentic specimen that had been prepared by enzymatic (PPL) hydrolysis of 2-benzyl-1,3-diacetoxypropane (Mori, K.; Chiba, N. Liebigs Ann. Chem. 1989, 957) followed by treatment of the resulting monoacetate with 3. Due to lack of reported data, the absolute configuration of 4b was tentatively assigned on the assumption that the enzymatic hydrolysis of 2-trimethylsilylmethyl-1,3-diacetoxypropane proceeds in the same sense as the other analogs.
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