Kinetics and Mechanism of the pyridinolysis of O,O-Dimethyl S-Aryl phosphorothioates in dimethyl sulfoxide

Bulletin of the Korean Chemical Society

Volumn 32, Issue 7, 2011, Pages 2339-2344

  Barai, Hasi Rani ^a   Lee, Hai Whang ^a  

^a Inha University   (South Korea)

Author keywords

Biphasic concave upward free energy correlation; O,O Dimethyl Z S aryl phosphorothioates; Phosphoryl transfer reaction; Pyridinolysis

Indexed keywords

BIPHASIC; BREAK-POINTS; CONCERTED MECHANISM; CROSS-INTERACTION CONSTANTS; ENERGY CORRELATION; KINETIC STUDY; KINETICS AND MECHANISM; LEAVING GROUPS; PHOSPHOROTHIOATES; PHOSPHORYL TRANSFER REACTION; PYRIDINOLYSIS; TRANSITION STATE;

PYRIDINE;

DIMETHYL SULFOXIDE;

EID: 79960492429     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2011.32.7.2339     Document Type: Article

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