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Volumn 30, Issue 4, 2009, Pages 975-978

Kinetics and mechanism of the aminolysis of dimethyl thiophosphinic chloride with anilines

Author keywords

Anilinolysis; Deuterium kinetic isotope effect; Dimethyl thiophosphinic chloride; Steric effect

Indexed keywords


EID: 70349766756     PISSN: 02532964     EISSN: 12295949     Source Type: Journal    
DOI: 10.5012/bkcs.2009.30.4.975     Document Type: Article
Times cited : (40)

References (44)
  • 29
    • 70349766344 scopus 로고    scopus 로고
    • Comparing the NBO charges of the reaction center P in the gas phase, the positive charge difference of P atom between P=S and P=O system is great, |Δδ| ≈ 0. 6: 1. 180 (1)< 1.793 (2) and 1.236 (3)< 1.844 (4), resulting in "thio effect". However, within each system, P=S or P=O system, the positive charge difference of P, |Δδ| = 0.05~0.06, is too small to be a decisive factor to decide the reactivity over steric factor
    • Comparing the NBO charges of the reaction center P in the gas phase, the positive charge difference of P atom between P=S and P=O system is great, |Δδ| ≈ 0.6: 1.180 (1) < 1.793 (2) and 1.236 (3) < 1.844 (4), resulting in "thio effect". However, within each system, P=S or P=O system, the positive charge difference of P, |Δδ| = 0.05~0.06, is too small to be a decisive factor to decide the reactivity over steric factor.
  • 32
    • 70349760121 scopus 로고    scopus 로고
    • 2O) is probably justified.
    • 2O) is probably justified.
  • 33
    • 0004284088 scopus 로고
    • Solute-Solvent Interactions
    • Coetzee J.F. Ritchie C.D.
    • Ritchie, C. D. Solute-Solvent Interactions, Coetzee, J. F.; Ritchie, C. D., Eds.; Marcel Dekker: New York, 1969; Ch. 4.
    • (1969) EdS Marcel Dekker: New York Ch4
    • Ritchie, C.D.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.