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Volumn 24, Issue 6, 2011, Pages 474-479

Kinetics and mechanism of the pyridinolysis of N-aryl-P,P-diphenyl phosphinic amides in dimethyl sulfoxide

Author keywords

biphasic concave upward free energy relationship; N aryl P,P diphenyl phosphinic amides; negative sign of lg; phosphoryl transfer reaction; pyridinolysis

Indexed keywords

BIPHASIC; BREAK-POINTS; CONCERTED MECHANISM; CROSS-INTERACTION CONSTANTS; ELECTRON-DONATING; ELECTRON-WITHDRAWING SUBSTITUENTS; ENERGY RELATIONSHIPS; HAMMETT PLOTS; KINETIC STUDY; KINETICS AND MECHANISM; LEAVING GROUPS; N-ARYL-P,P-DIPHENYL PHOSPHINIC AMIDES; NUCLEOPHILIC ATTACK; PHOSPHORYL TRANSFER; PYRIDINOLYSIS; REACTION CENTER;

EID: 79958210192     PISSN: 08943230     EISSN: 10991395     Source Type: Journal    
DOI: 10.1002/poc.1788     Document Type: Article
Times cited : (34)

References (62)
  • 27
    • 20644453756 scopus 로고    scopus 로고
    • Herein, the authors showed that substituent 4-CN in pyridine has strong para π-acceptor ability.
    • H. J. Koh, K. L. Han, H. W. Lee, I. Lee, J. Org. Chem. 1998, 63, 9834-9839. Herein, the authors showed that substituent 4-CN in pyridine has strong para π-acceptor ability.
    • (1998) J. Org. Chem. , vol.63 , pp. 9834-9839
    • Koh, H.J.1    Han, K.L.2    Lee, H.W.3    Lee, I.4
  • 33
    • 79958213250 scopus 로고    scopus 로고
    • note
    • N2 pathways.
  • 42
    • 79958196893 scopus 로고    scopus 로고
    • note
    • N2 pathways are generally in the range of -0.1 to -0.3.
  • 43
    • 79958216502 scopus 로고    scopus 로고
    • Ref. 2, Chapter 7
    • Ref. 2, Chapter 7.
  • 62
    • 79958228012 scopus 로고    scopus 로고
    • note
    • N2 pathways.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.