PH-switchable inversion of the metal-centered chirality of metallabenzenes: Opposite stereodynamics in reactions of ruthenabenzene with L -and D -cysteine

Chemistry - A European Journal

Volumn 17, Issue 8, 2011, Pages 2420-2427

  Lin, Ran ^a   Zhang, Hong ^a   Li, Shunhua ^a,b   Chen, Leiqi ^a   Zhang, Weiguang ^c   Wen, Ting Bin ^a   Zhang, Hui ^a   Xia, Haiping ^a  

^a XIAMEN UNIVERSITY   (China)

^b XIAMEN UNIVERSITY   (China)

^c SOUTH CHINA NORMAL UNIVERSITY   (China)

Author keywords

amino acids; chirality; metallacycles; molecular probes; ruthenium

Indexed keywords

AQUEOUS SOLUTIONS; BIOACTIVE MOLECULES; CHEMICAL INTERACTIONS; DYNAMIC INVERSION; ELECTROSTATIC INTERACTIONS; EPIMERIZATION; INVERSION PROCESS; L-CYSTEINE; METALLACYCLES; MOLECULAR PROBES; PH ADJUSTMENT; PHENANTHROLINES; PHYSIOLOGICAL PH; STEREODYNAMICS; SWITCHABLE;

CHIRALITY; CHLORINE; ENANTIOMERS; PH; PROBES; RUTHENIUM; STEREOCHEMISTRY; X RAY DIFFRACTION;

AMINO ACIDS;

BENZENE DERIVATIVE; CYSTEINE; DRUG DERIVATIVE; ORGANOMETALLIC COMPOUND; PHENANTHROLINE DERIVATIVE; RUTHENIUM;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH; STEREOISOMERISM; X RAY CRYSTALLOGRAPHY;

BENZENE DERIVATIVES; CRYSTALLOGRAPHY, X-RAY; CYSTEINE; HYDROGEN-ION CONCENTRATION; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PHENANTHROLINES; RUTHENIUM; STEREOISOMERISM;

EID: 79951613197     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201001867     Document Type: Article

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