Ligands rock & roll: Stepwise twisting of two cis-coordinated lopsided N-heterocycles in an octahedral bis(2-phenylazopyridine)-ruthenium(II) complex with seven atropisomers

Chemistry - A European Journal

Volumn 11, Issue 4, 2005, Pages 1325-1340

  Velders, Aldrik H ^a,b   Hotze, Anna C G ^a   Reedijk, Jan ^a  

^a LEIDEN UNIVERSITY   (Netherlands)

^b UNIVERSITY OF TWENTE   (Netherlands)

Author keywords

Atropisomerism; Bioinorganic chemistry; DNA model bases; NMR spectroscopy; Ruthenium

Indexed keywords

CELLS; COOLING; DNA; ISOMERIZATION; NUCLEAR MAGNETIC RESONANCE; RESONANCE; RUTHENIUM; TOXICITY; TUMORS;

ATROPISOMERS; CORDINATION COMPOUND; DNA MODELS; LIGANDS;

ISOMERS;

1 METHYLBENZIMIDAZOLE; BENZIMIDAZOLE DERIVATIVE; BIS(2 PHENYLAZOPYRIDINE)RUTHENIUM DERIVATIVE; COORDINATION COMPOUND; DNA; HETEROCYCLIC COMPOUND; RUTHENIUM COMPLEX; UNCLASSIFIED DRUG;

ARTICLE; ATROPISOMER; CHEMICAL REACTION KINETICS; CIS ISOMER; COOLING; CYTOTOXICITY; ISOMER; ISOMERISM; LIGAND BINDING; LOW TEMPERATURE PROCEDURES; NUCLEAR OVERHAUSER EFFECT; PROCESS MODEL; PROTON NUCLEAR MAGNETIC RESONANCE; SIGNAL TRANSDUCTION; TEMPERATURE MEASUREMENT;

DNA; HETEROCYCLIC COMPOUNDS; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PROTONS; REFERENCE STANDARDS; RUTHENIUM; SENSITIVITY AND SPECIFICITY; STEREOISOMERISM; STRUCTURE-ACTIVITY RELATIONSHIP; TEMPERATURE;

EID: 14544291486     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200400590     Document Type: Article

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