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Volumn 22, Issue 17, 2010, Pages 4854-4866

Solution reactions of a Bis(pyrrolylaldiminate)copper(II) complex with peralkyl zinc, aluminum, and boron reagents: Investigation of the pathways responsible for copper metal deposition

Author keywords

[No Author keywords available]

Indexed keywords

ALKYL COMPLEXES; BOND FORMING; BORON REAGENTS; COPPER (II); COPPER COMPLEXES; COPPER DEPOSITION; COPPER METAL; ELEVATED TEMPERATURE; HYDRIDE ELIMINATION; LIGAND REDISTRIBUTION; PURE COMPOUNDS; REACTION BYPRODUCTS; REDUCTIVE ELIMINATION; ROOM TEMPERATURE; SOLUTION REACTION; THERMALLY STABLE; TWO STAGE;

EID: 77956404703     PISSN: 08974756     EISSN: 15205002     Source Type: Journal    
DOI: 10.1021/cm101443x     Document Type: Article
Times cited : (47)

References (77)
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    • 2, but whether such a species can be observed spectroscopically depends on its thermal stability
    • 2, but whether such a species can be observed spectroscopically depends on its thermal stability.
  • 24
    • 0035905509 scopus 로고    scopus 로고
    • The Cu-Cu distance in complex 8 could indicate the presence of a Cu-Cu interaction, especially given the extent to which the two copper centres bend towards one another [N(1)-N(2) 3.064 Å; Cu(1)-Cu(2) 2.531 Å; N(11)-N(12) 3.088 Å]. However, the subject of cuprophilic interactions has been one of some controversy
    • The Cu-Cu distance in complex 8 could indicate the presence of a Cu-Cu interaction, especially given the extent to which the two copper centres bend towards one another [N(1)-N(2) 3.064 Å; Cu(1)-Cu(2) 2.531 Å; N(11)-N(12) 3.088 Å]. However, the subject of cuprophilic interactions has been one of some controversy: Hermann, H. L.; Boche, G.; Schwerdtfeger, P. Chem. - Eur. J. 2001, 7, 5333
    • (2001) Chem. - Eur. J. , vol.7 , pp. 5333
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    • iPr) in the presence or absence of a phosphine ligand
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    • Ikariya, T.1    Yamamoto, A.2
  • 41
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    • Complex 9c also formed in small amounts after 3 days at room temperature
    • Complex 9c also formed in small amounts after 3 days at room temperature.
  • 42
    • 77956402963 scopus 로고    scopus 로고
    • 6, indicative of copper reduction via reductive elimination rather than bond homolysis pathways
    • 6, indicative of copper reduction via reductive elimination rather than bond homolysis pathways.
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    • i Pr] by addition of a small amount of THF
    • i Pr] by addition of a small amount of THF.
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    • 2] (L = N -2,6-diisopropylphenyl-2-pyrrolylaldiminate and the 5- tert -butyl-substituted analogue), have been reported. (41)
    • 2] (L = N -2,6-diisopropylphenyl-2-pyrrolylaldiminate and the 5- tert -butyl-substituted analogue), have been reported. (41)
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    • The refined cell had a greater volume than the original because powder diffraction was performed at room temperature, whereas the single-crystal experiment was performed at low temperature
    • The refined cell had a greater volume than the original because powder diffraction was performed at room temperature, whereas the single-crystal experiment was performed at low temperature.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.