Synthesis of a novel volatile platinum complex for use in CVD and a study of the mechanism of its thermal decomposition in solution

Journal of the American Chemical Society

Volumn 118, Issue 11, 1996, Pages 2634-2643

  Tagge, Christopher D ^a   Simpson, Robert D ^a   Bergman, Robert G ^a   Hosteller, Michael J ^b   Girolami, Gregory S ^b   Nuzzo, Ralph G ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of Illinois at Urbana Champaign   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; CHARACTERIZATION; CHEMICAL VAPOR DEPOSITION; DECOMPOSITION; REACTION KINETICS; SOLUTIONS; SOLVENTS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS;

DEUTERIUM ISOTOPE EFFECT; HYDRIDE ELIMINATION; VOLATILE PLATINUM COMPLEXES;

PLATINUM COMPOUNDS;

PLATINUM COMPLEX;

ARTICLE; DRUG STABILITY; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; THERMOSTABILITY;

EID: 15844413522     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9526527     Document Type: Article

References (47)

1. Jensen, K. S., Kern, W. In Thin Film Processes; Vossen, J. L., Kern, W., Eds : Academic Press: Boston, 1991, Vol. II, pp 283-353.
2. Bindra, P., Roldan, J. J. Electrochem. Soc. 1985, 132, 2581-2589.
3. Green, M. L , Levy, R. A. J. Met. 1985, 37, 63-71.
4. Shibli, S. M A ; Noel, M. J. Power Sources 1993, 45, 139-152.
5. Zimmerman, J. H. J. Power Sources 1991, 36, 253-267.
6. Dosst, C.; Psaro, R ; Bartsch, A., Fusi, A.; Sordelli, L., Ugo, R.; Bellatreccia, M.; Zanoni, R.; Vlaic, G. J. Catal. 1994, 145, 377-383.
7. Bradley, D C Polyhedron 1994, 13, 1111-1121
8. Dryden, N. H.; Kumar, R.; Ou, E.; Rashidi, M., Roy, S.; Norton, P R., Puddephatt, R. J. Chem. Mater. 1991, 3, 677-685.
9. Gozum, J. E., Pollina, D. M., Jensen, J. A.; Girolami, G S. J. Am. Chem. Soc. 1988, 110, 2688-2689
10. Puddephatt, R. J. Polyhedron 1994, 13, 1233-1234.
11. Xue, Z.; Strouse, M. J.; Shuh, D K.; Knobler, C. B.; Kaesz, H. D ; Hicks, R. F ; Williams, R S. J. Am. Chem. Soc. 1989, 111, 8779-8784.
12. Xue, Z., Thridanam, H ; Kaesz, H. D ; Hicks, R F. Chem. Mater. 1992, 4, 162-166.
13. Kumar, R ; Roy, S ; Rashidi, M., Puddephatt, R. J Polyhedron 1989, 8, 551-553.
14. Albright, T. A., Hoffmann, R., Thibeault, J C., Thorn, D. L. J. Am Chem Soc 1979, 101, 3801-3812.
15. Whitesides, G. M.; Hackett, M ; Brainard, R. L.; Lavalleye, J P. P. M ; Sowinsky, A. F.; Izumi, A. N., Moore, S. S.; Brown, D. W., Staudt, E. M. Organometallics 1985, 4, 1819-1830.
16. Green, M.; Grove, D. M ; Howard, J. A. K.; Spencer, J. L.; Stone, F. C. A J. Chem. Soc., Chem. Commun. 1976, 759-760.
17. At room temperature the NMR spectra are broad. At low temperature a small amount (<5%) of a minor isomer was detected. The fluxional process was not investigated.
18. Isomerization to give the E isomer is common for alkyne insertion reactions (see refs 19-22).
19. Huggins, J. M.; Bergman, R. G. J. Am. Chem. Soc. 1981, 103, 3002-3011.
20. Samsel, E G.; Norton. J R J. Am. Chem. Soc. 1984, 106, 5505-5512
21. Attig, T. G.; Clark, H. C.; Wong, C S Can J. Chem. 1977, 55, 189-198.
22. Clark, H C.; Fiess, P. L ; Wong, C. S. Can. J Chem. 1977, 55, 177-188.
23. Since 1,4-pentadiene is produced during the course of the reaction, the value for [1,4-pentadiene] was set to 0.014 M. the average of the amount produced However, use of values ranging from 0 0001 to 0 028 M for this concentration gives similar plots.
24. 8 organometallic complexes, having strong σ-donating, trans-activating alkyl ligands, which undergo substitution by dissociation of a neutral ligand to give a three-coordinate 14-electron intermediate (see refs 25-30).
25. Alibrandi, G.; Bruno, G.; Lanza, S ; Minniti, D., Romeo, R.; Tobe, M. L. Inorg. Chem. 1987, 26, 185-190
26. Brainard, R. L.; Miller, T. M.; Whitesides, G. M Organometallics 1986, 5, 1481-1490.
27. Frey, U.; Helm, L.; Merbach, A. E., Romeo, R. J Am. Chem. Soc. 1989, 111, 8161-8165.
28. Lanza, S.; Minniti, D.; Romeo, R.; Moore, P.; Sachinidis, J.; Tobe, M. L J. Chem. Soc., Chem. Commun. 1984, 542-543.
29. Minniti, D.; Alibrandi, G., Tobe, M. L.; Romeo, R Inorg. Chem. 1987, 26, 3956-3958.
30. Minniti, D. Inorg. Chem. 1994, 33, 2631-2634.
31. Thorn, D. L ; Hoffmann, R. J. Am. Chem. Soc. 1978, 100, 2079-2090.
32. Brainard, R. L ; Whitesides, G. M. Organometallics 1985, 4, 1550-1557.
33. McCarthy, T. J.; Nuzzo, R. G., Whitesides, G. M. J. Am. Chem. Soc. 1981, 103, 1676-1678
34. Whitesides, G. M., Gaasch, J. F; Stedronsky, E. R J. Am. Chem. Soc. 1972, 94, 5258-5270
35. McDermott, J. X.; White, J. F . Whitesides, G M. J. Am. Chem. Soc. 1976, 98, 6521-6528.
36. Miller, T. M., Whitesides, G M. Organometallics s 1986, 5, 1473-1480.
37. Ermer, S. P.; Struck, G. E.; Bitler, S P.; Richards, R., Bau, R.; Flood, T. C. Organometallics 1993, 12, 2634-2643
38. Jones, W. D.; Feher, F J. J. Am. Chem Soc. 1984, 106, 1650-1663
39. Chaudhury, N.; Puddephatt, R. J. J. Organomet. Chem 1975, 87, C45-C47
40. A mechanism involvig rapid, reversible alkyne insertion would also account for the observed effect of diphenylacetylene concentration, However, to our know, ledge, there have been no reports of facile β-hydride elimination from a vinyl complex.
41. Parshall, G. W.; Ittel, S D. Homogeneous Catalysis, 2nd ed., John Wiley and Sons, Inc . New York, 1992.
42. Hostetler, M. J.; Nuzzo, R. G.; Girolami, G. S J. Am. Chem. Soc. 1995, 117, 1814-1827.
43. Barnager, A. M., Bergman, R. G. J. Am. Chem. Soc. 1994, 116, 3822-3835.
44. Crawford, R. J.; Lutene, S.; Tokunaga, H. Can. J. Chem. 1977, 55, 3951-3954.
45. Lukes, R.; Hofman, J. Chem. Ber. 1960, 93, 2556-2561.
46. Walker, N.; Stuart, D. Acta Crystallogr. 1983, A39, 159.
47. Cromer, D. T.; Waber, J. T. International Tables for X-Ray Crystallography; The Kynoch Press: Birmingham, England, 1974; Vol. IV.