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Volumn 118, Issue 11, 1996, Pages 2634-2643

Synthesis of a novel volatile platinum complex for use in CVD and a study of the mechanism of its thermal decomposition in solution

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; CHARACTERIZATION; CHEMICAL VAPOR DEPOSITION; DECOMPOSITION; REACTION KINETICS; SOLUTIONS; SOLVENTS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS;

EID: 15844413522     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9526527     Document Type: Article
Times cited : (44)

References (47)
  • 1
    • 84940826989 scopus 로고
    • Vossen, J. L., Kern, W., Eds : Academic Press: Boston
    • Jensen, K. S., Kern, W. In Thin Film Processes; Vossen, J. L., Kern, W., Eds : Academic Press: Boston, 1991, Vol. II, pp 283-353.
    • (1991) Thin Film Processes , vol.2 , pp. 283-353
    • Jensen, K.S.1    Kern, W.2
  • 17
    • 15844412466 scopus 로고    scopus 로고
    • At room temperature the NMR spectra are broad. At low temperature a small amount (<5%) of a minor isomer was detected. The fluxional process was not investigated
    • At room temperature the NMR spectra are broad. At low temperature a small amount (<5%) of a minor isomer was detected. The fluxional process was not investigated.
  • 18
    • 15844379743 scopus 로고    scopus 로고
    • Isomerization to give the E isomer is common for alkyne insertion reactions (see refs 19-22)
    • Isomerization to give the E isomer is common for alkyne insertion reactions (see refs 19-22).
  • 23
    • 15844400721 scopus 로고    scopus 로고
    • Since 1,4-pentadiene is produced during the course of the reaction, the value for [1,4-pentadiene] was set to 0.014 M. the average of the amount produced However, use of values ranging from 0 0001 to 0 028 M for this concentration gives similar plots
    • Since 1,4-pentadiene is produced during the course of the reaction, the value for [1,4-pentadiene] was set to 0.014 M. the average of the amount produced However, use of values ranging from 0 0001 to 0 028 M for this concentration gives similar plots.
  • 24
    • 15844369260 scopus 로고    scopus 로고
    • 8 organometallic complexes, having strong σ-donating, trans-activating alkyl ligands, which undergo substitution by dissociation of a neutral ligand to give a three-coordinate 14-electron intermediate (see refs 25-30)
    • 8 organometallic complexes, having strong σ-donating, trans-activating alkyl ligands, which undergo substitution by dissociation of a neutral ligand to give a three-coordinate 14-electron intermediate (see refs 25-30).
  • 40
    • 15844368523 scopus 로고    scopus 로고
    • A mechanism involvig rapid, reversible alkyne insertion would also account for the observed effect of diphenylacetylene concentration, However, to our know, ledge, there have been no reports of facile β-hydride elimination from a vinyl complex
    • A mechanism involvig rapid, reversible alkyne insertion would also account for the observed effect of diphenylacetylene concentration, However, to our know, ledge, there have been no reports of facile β-hydride elimination from a vinyl complex.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.