Iridium compounds with κ- P,P,Si (biPSi) pincer ligands: Favoring reactive structures in unsaturated complexes

Journal of the American Chemical Society

Volumn 132, Issue 26, 2010, Pages 9111-9121

  Sola, Eduardo ^a   García Camprubí, Alba ^a   Andrés, José L ^a   Martín, Marta ^a   Plou, Pablo ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENYL; ALKYLIDENES; ANTI ISOMERS; CHLORINATED SOLVENT; COORDINATE COMPLEXES; COORDINATION PROCESS; COORDINATION PROPERTIES; COORDINATION SPHERE; DIPHENYLACETYLENE; DYNAMIC BEHAVIORS; EQUATORIAL PLANES; EQUILIBRIUM POSITIONS; ETHYL DIAZOACETATE; EXPERIMENTAL OBSERVATION; H-BONDS; HYDROGEN ATOMS; INSERTION PROCESS; INSERTION PRODUCTS; KINETIC BARRIER; LIGAND COORDINATION; MP2 CALCULATIONS; OXIDATIVE ADDITIONS; PINCER LIGANDS; POTENTIAL LIGAND; PYRAMIDAL STRUCTURES; SECOND ORDERS; STERIC ORIGIN; STRUCTURAL DIFFERENCES; SYN-ISOMERS; TIME-SCALES; TRANSITION STATE;

ACETYLENE; ELECTRON TRANSITIONS; EQUILIBRIUM CONSTANTS; IRIDIUM; IRIDIUM COMPOUNDS; ISOMERIZATION; LIGANDS; LIGHTING; SILICON; SILICON COMPOUNDS; SOLVENTS; SPHERES; UNSATURATED COMPOUNDS;

ISOMERS;

ACETYLENE DERIVATIVE; ALKENYL GROUP; ALKYL GROUP; CHLORINATED HYDROCARBON; DIAZOACETIC ACID ETHYL ESTER; DIPHENYLACETIC ACID; HALOGEN; HYDROGEN; IRIDIUM COMPLEX; SILICON DERIVATIVE; SOLVENT;

ADDITION REACTION; ARTICLE; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; ENTHALPY; ENTROPY; ISOMER; ISOMERIZATION; MOLECULAR DYNAMICS; OXIDATION; POLYMERIZATION; QUALITATIVE ANALYSIS; QUANTITATIVE ANALYSIS; THERMODYNAMICS;

EID: 77954305276     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja102479h     Document Type: Article

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