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For examples involving N-H bond activation of ammonia by multimetallic cluster species, see: and references therein
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For examples involving N-H bond activation of ammonia by multimetallic cluster species, see:Nakajima, Y.; Kameo, H.; Suzuki, H. Angew. Chem., Int. Ed. 2006, 45, 950, and references therein.
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For related examples involving the insertion of a main group fragment into a N-H bond of ammonia, see:(a)
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For related examples involving the insertion of a main group fragment into a N-H bond of ammonia, see:(a) Frey, G. D.; Lavallo, V.; Donnadieu, B.; Schoeller, W. W.; Bertrand, G. Science 2007, 316, 439.
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70349937780
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note
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8
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27
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70349964285
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note
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8
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28
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70349950445
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note
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2 fragments.
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29
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70349959638
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note
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8
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30
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0034623550
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I species (M = Rh, Ir) have been proposed as reactive intermediates in E-H bond activation reactions:(a)
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I species (M = Rh, Ir) have been proposed as reactive intermediates in E-H bond activation reactions:(a) Kanzelberger, M.; Singh, B.; Czerw, M.; Krogh-Jespersen, K.; Goldman, A. S. J. Am. Chem. Soc. 2000, 122, 11017.
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Kanzelberger, M.1
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2342434304
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(b) Göttker-Schnetmann, I.; White, P. S.; Brookhart, M. Organometallics 2004, 23, 1766.
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Göttker-Schnetmann, I.1
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33644937143
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(c) Gatard, S.; Celenligil-Cetin, R.; Guo, C.; Foxman, B. M.; Ozerov, O. V. J. Am. Chem. Soc. 2006, 128, 2808.
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Verat, A.Y.1
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Zhou, J.; Hartwig, J. F. Angew. Chem., Int. Ed. 2008, 47, 5783.
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Zhou, J.1
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36
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70349939360
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note
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3 Ir(I) adducts 8 and 9 that could result from reductive elimination of ammonia was confirmed via independent synthesis.
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