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Volumn 16, Issue 26, 1997, Pages 5669-5680

Phosphinoalkylsilyl complexes. 12. Stereochemistry of the tridentate bis(diphenylphosphinopropyl)silyl (biPSi) framework: Complexation that introduces "face discrimination" at coordinatively unsaturated metal centers. X-ray crystal and molecular structures of Pt[SiMe(CH2CH2CH2PPh2) 2]Cl

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EID: 0000390929     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970518k     Document Type: Article
Times cited : (66)

References (54)
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    • Burk, M. J.; McGrath, M. P.; Wheeler, R.; Crabtree, R. H. J. Am. Chem. Soc. 1988, 110, 5034. Sargent, A. L.; Hall, M. B.; Guest, M. F. J. Am. Chem. Soc. 1992, 114, 517. Sargent, A. L.; Hall, M. B. Inorg. Chem. 1992, 31, 317.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 517
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    • Burk, M. J.; McGrath, M. P.; Wheeler, R.; Crabtree, R. H. J. Am. Chem. Soc. 1988, 110, 5034. Sargent, A. L.; Hall, M. B.; Guest, M. F. J. Am. Chem. Soc. 1992, 114, 517. Sargent, A. L.; Hall, M. B. Inorg. Chem. 1992, 31, 317.
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    • See: Heinekey, D. M.; Hinkle, A. S.; Close, J. D. J. Am. Chem. Soc. 1996, 117, 5353. Two-bond H-H coupling has rarely been observed in cis dihydrido complexes because the two H atoms are most commonly chemically equivalent (see also refs 9 and 31 for examples where this is not so); corresponding data for related trans dihydrido complexes remain exceedingly rare.
    • (1996) J. Am. Chem. Soc. , vol.117 , pp. 5353
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