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Volumn 20, Issue 10, 2001, Pages 1898-1900

Stereomutation at an octahedral transition-metal center: Energetics of hydride transit between syn and anti faces of the bis(diphenylphosphinopropyl)(methyl)silyl (biPSi) complex RuH(biPSi)(CO)2

Author keywords

[No Author keywords available]

Indexed keywords

BISDIPHEHYLPHOSPHINOPROPYLMETHYLSILYL; OCTAHEDRAL TRANSITION METAL CENTER; PHOSPHINOALKYLSILYL COMPLEX; STEREOMUTATION;

EID: 0035858947     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0100939     Document Type: Article
Times cited : (30)

References (44)
  • 14
    • 0011483727 scopus 로고    scopus 로고
    • note
    • 6) δ 32.9. The Ph hydrogens were observed as complex multiplets in the δ 7.0-8.0 range; the methylene hydrogens for 3-a were obscured by those due to 3-s.
  • 15
    • 0011445150 scopus 로고    scopus 로고
    • note
    • 1H NMR signals are assigned to Ph ortho hydrogens in 3-s and 3-a.
  • 16
    • 0011437698 scopus 로고    scopus 로고
    • note
    • +.
  • 27
    • 0011492155 scopus 로고
    • and references therein.
    • For a further discussion see also: Hostetler, M. J., Bergman, R. G. J. Am. Chem. Soc. 1992, 114, 7629, and references therein.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 7629
    • Hostetler, M.J.1    Bergman, R.G.2
  • 28
    • 0011436433 scopus 로고    scopus 로고
    • note
    • II formyl.
  • 34
    • 0011436434 scopus 로고    scopus 로고
    • note
    • Which in order to interconvert 3-s:3-a would also be required to mediate a crossover between the diastereomeric reaction manifolds that lead respectively to 3-s and 3-a, rather than following the microscopic reverse of the elimination step, which would simply regenerate the original stereochemistry (i.e., 3-s).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.