메뉴 건너뛰기




Volumn 122, Issue 8, 2000, Pages 1816-1817

The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination [8]

Author keywords

[No Author keywords available]

Indexed keywords

CARBON; HYDROGEN; IRIDIUM COMPLEX; SILANE DERIVATIVE; SILICON;

EID: 0343384167     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992954z     Document Type: Letter
Times cited : (148)

References (28)
  • 1
    • 0000820085 scopus 로고
    • For recent reviews of C-H activation see: (a) Arndtsen, B. A.; Bergman, R. G.; Mobley, T. A., Peterson, T. H. Acc. Chem. Res. 1995, 28, 154. (b) Sen, A. New Approaches in C-H Activation of Alkanes in Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Two Volumes; Cornils, B., Herrmann, W. A., Eds.; Wiley- VCH: New York, 1996; pp 1081-1092. (c) Shilov, A. E.; Shulpin, G. B. Chem. Rev. 1997, 97, 2879. Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. Angew. Chem., Int. Ed. Engl. 1998, 37, 2181.
    • (1995) Acc. Chem. Res. , vol.28 , pp. 154
    • Arndtsen, B.A.1    Bergman, R.G.2    Mobley, T.A.3    Peterson, T.H.4
  • 2
  • 3
    • 0012233552 scopus 로고    scopus 로고
    • For recent reviews of C-H activation see: (a) Arndtsen, B. A.; Bergman, R. G.; Mobley, T. A., Peterson, T. H. Acc. Chem. Res. 1995, 28, 154. (b) Sen, A. New Approaches in C-H Activation of Alkanes in Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Two Volumes; Cornils, B., Herrmann, W. A., Eds.; Wiley- VCH: New York, 1996; pp 1081-1092. (c) Shilov, A. E.; Shulpin, G. B. Chem. Rev. 1997, 97, 2879. Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. Angew. Chem., Int. Ed. Engl. 1998, 37, 2181.
    • (1997) Chem. Rev. , vol.97 , pp. 2879
    • Shilov, A.E.1    Shulpin, G.B.2
  • 4
    • 0000738406 scopus 로고    scopus 로고
    • For recent reviews of C-H activation see: (a) Arndtsen, B. A.; Bergman, R. G.; Mobley, T. A., Peterson, T. H. Acc. Chem. Res. 1995, 28, 154. (b) Sen, A. New Approaches in C-H Activation of Alkanes in Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook in Two Volumes; Cornils, B., Herrmann, W. A., Eds.; Wiley- VCH: New York, 1996; pp 1081-1092. (c) Shilov, A. E.; Shulpin, G. B. Chem. Rev. 1997, 97, 2879. Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. Angew. Chem., Int. Ed. Engl. 1998, 37, 2181.
    • (1998) Angew. Chem., Int. Ed. Engl. , vol.37 , pp. 2181
    • Stahl, S.S.1    Labinger, J.A.2    Bercaw, J.E.3
  • 10
    • 0343609159 scopus 로고    scopus 로고
    • For literature citations for stable Ir(V) species see ref 6, footnotes 13 and 18-31
    • For literature citations for stable Ir(V) species see ref 6, footnotes 13 and 18-31.
  • 11
    • 0343173662 scopus 로고    scopus 로고
    • For literature precedent for postulated Ir(V) species see ref 6, footnotes 13-17
    • For literature precedent for postulated Ir(V) species see ref 6, footnotes 13-17.
  • 14
    • 0001565235 scopus 로고
    • Diversi, P.; lacoponi, S.; Ingrosso, G.; Laschi, F.; Lucherini, A.; Pinzino, C.; Uccello-Barretta, G.; Zanello, P. Organometallics 1995, 14, 4, 3275. Note added in proof: These studies have recently been extended to the reactions of dialkyliridium complexes with silanes in the presence of one- electron oxidants: Diversi, P.; Marchetti, F.; Ermini, V.; Matteoni, S. J. Organomet. Chem. 2000, 593-594, 154.
    • (1995) Organometallics , vol.14 , Issue.4 , pp. 3275
    • Diversi, P.1    Lacoponi, S.2    Ingrosso, G.3    Laschi, F.4    Lucherini, A.5    Pinzino, C.6    Uccello-Barretta, G.7    Zanello, P.8
  • 15
    • 0034649980 scopus 로고    scopus 로고
    • Diversi, P.; lacoponi, S.; Ingrosso, G.; Laschi, F.; Lucherini, A.; Pinzino, C.; Uccello-Barretta, G.; Zanello, P. Organometallics 1995, 14, 4, 3275. Note added in proof: These studies have recently been extended to the reactions of dialkyliridium complexes with silanes in the presence of one-electron oxidants: Diversi, P.; Marchetti, F.; Ermini, V.; Matteoni, S. J. Organomet. Chem. 2000, 593-594, 154.
    • (2000) J. Organomet. Chem. , vol.593-594 , pp. 154
    • Diversi, P.1    Marchetti, F.2    Ermini, V.3    Matteoni, S.4
  • 16
    • 0342304113 scopus 로고    scopus 로고
    • note
    • 4.
  • 25
    • 0000652867 scopus 로고    scopus 로고
    • (h) Petri, S. H. A.; Eikenberg, D.; Neumann, B.; Stammler, H. G.; Jutz, P. Organometallics 1999, 18, 2615. Just prior to discovery of the iridium silylene complex presented here, the first example of an iridium complex containing such a ligand was synthesized: Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871.
    • (1999) Organometallics , vol.18 , pp. 2615
    • Petri, S.H.A.1    Eikenberg, D.2    Neumann, B.3    Stammler, H.G.4    Jutz, P.5
  • 26
    • 0033610440 scopus 로고    scopus 로고
    • (h) Petri, S. H. A.; Eikenberg, D.; Neumann, B.; Stammler, H. G.; Jutz, P. Organometallics 1999, 18, 2615. Just prior to discovery of the iridium silylene complex presented here, the first example of an iridium complex containing such a ligand was synthesized: Peters, J. C.; Feldman, J. D.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9871.
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 9871
    • Peters, J.C.1    Feldman, J.D.2    Tilley, T.D.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.