Dimerization of alkynes promoted by a pincer-ligated iridium complex. C-C reductive elimination inhibited by steric crowding

Journal of the American Chemical Society

Volumn 129, Issue 4, 2007, Pages 853-866

  Ghosh, Rajshekhar ^a   Zhang, Xiawei ^a   Achord, Patrick ^a   Emge, Thomas J ^a   Krogh Jespersen, Karsten ^a   Goldman, Alan S ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BOND FORMATION; PHENYLACETYLENE; PINCER LIGATED SPECIES; STERIC CROWDING;

CHEMICAL BONDS; COMPLEXATION; COMPUTATIONAL METHODS; DIMERIZATION; IRIDIUM COMPOUNDS; MOLECULAR STRUCTURE;

HYDROCARBONS;

1,4 PHENYL BUT 3 ENE 1 YNE; ALKYNE DERIVATIVE; CARBON; ENYNE DERIVATIVE; IRIDIUM COMPLEX; PHENYLACETYLENE; UNCLASSIFIED DRUG; VINYL DERIVATIVE;

ADDITION REACTION; ARTICLE; CALCULATION; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; DIMERIZATION; ELIMINATION REACTION; MOLECULAR STABILITY; REDUCTION KINETICS; STEREOCHEMISTRY;

EID: 33846611597     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0647194     Document Type: Article

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