Constructing quaternary centers of chirality: The lanthanide way to trifluoromethyl-substituted tertiary alcohols

Synthesis

Volumn , Issue 11, 2010, Pages 1909-1923

  Tur, Fernando ^a   Mansilla, Javier ^a   Lillo, Victor J ^a   Saá, José M ^a  

^a UNIVERSITAT DE LES ILLES BALEARS   (Spain)

Author keywords

Alcohols; Amino alcohols; Chiral lanthanide complexes; Enantioselective catalysis; Fluorine

Indexed keywords

ABSOLUTE CONFIGURATION; ALKYNYLS; AMINO ALCOHOLS; BINAPHTHALENES; CARBON NUCLEOPHILES; CHEMICAL YIELDS; ENANTIOSELECTIVE ADDITION; ENANTIOSELECTIVE CATALYSIS; LANTHANIDE COMPLEX; LANTHANIDES; LANTHANUM COMPLEX; NICKEL BORIDE; NITROALDOL; NITROMETHANE; QUATERNARY CENTERS; TERTIARY ALCOHOLS; TETRAHYDROBORATE; TRIFLUOROMETHYL; TRIFLUOROMETHYLKETONE;

ACETONITRILE; AMINES; BORIDES; CATALYSIS; CATALYSTS; CHIRALITY; CHLORINE COMPOUNDS; ENANTIOMERS; ENANTIOSELECTIVITY; FLUORINE; HYDROCARBONS; KETONES; METHANOL; NAPHTHALENE; NICKEL ALLOYS; RARE EARTH ELEMENTS; STEREOCHEMISTRY;

ORGANIC POLYMERS;

1,1,1 TRIFLUORO 2 (4 FLUOROPHENYL) 3 NITROPROPAN 2 OL; 1,1,1 TRIFLUORO 2 (NITROMETHYL) 4 PHENYLBUT 3 YN 2 OL; 1,1,1 TRIFLUORO 2 (NITROMETHYL)BUTAN 2 OL; 1,1,1 TRIFLUORO 3 NITRO 2 [3 (TRIFLUOROMETHYL)PHENYL]PROPAN 2 OL; 1,1,1 TRIFLUORO 3 NITRO 2 PHENYLPROPAN 2 OL; 1,8 BIS(DIMETHYLAMINO)NAPHTHALENE; 2 (4 TERT BUTYLPHENYL) 1,1,1 TRIFLUORO 3 NITROPROPAN 2 OL; 2 (AMINOMETHYL) 1,1,1 TRIFLUORO 4 PHENYLBUTAN 2 OL; 2 BENZYL 1,1,1 TRIFLUORO 3 NITROPROPAN 2 OL; 3 AMINO 1,1,1 TRIFLUORO 2 PHENYLPROPAN 2 OL; 3 AMINO 2 (4 TERT BUTYLPHENYL) 1,1,1 TRIFLUOROPROPAN 2 OL; 3 AMINO 2 BENZYL 1,1,1 TRIFLUOROPROPAN 2 OL; 3,3' BIS[(DIETHYLAMINO)METHYL] 1,1' BINAPHTHALENE 2,2' DIOL; ACETONITRILE; AMINOALCOHOL; LANTHANIDE; METHANOL; NICKEL BORIDE; NICKEL CHLORIDE; NITROMETHANE; SODIUM BOROHYDRIDE; UNCLASSIFIED DRUG;

ALDOL REACTION; ALKYLATION; ARTICLE; CATALYST; CHEMICAL STRUCTURE; CHIRALITY; CLINICAL PROTOCOL; ENANTIOMER; ENANTIOSELECTIVITY; ENE REACTION; FRIEDEL CRAFTS REACTION; NITROALDOL REACTION; STOICHIOMETRY; SYNTHESIS;

EID: 77952754566     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1218751     Document Type: Article

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