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note
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Preliminary optimization of the reaction solvent, chiral ligand, and additives in the phenylation reaction has not improved the enantioselectivity so far.
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For catalytic enantioselective arylation of activated ketones, see:
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For catalytic enantioselective arylation of activated ketones, see:. Shintani R., Inoue M., and Hayashi T. Angew. Chem., Int. Ed. 45 (2006) 3353
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For catalytic enantioselective synthesis of 5 using Sharpless dihydroxylation as a key step, see:. Bennani Y.L., Vanhessche K.P.M., and Sharpless K.B. Tetrahedron: Asymmetry 5 (1994) 1473
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For a review of catalytic enantioselective alkynylation of ketones, see:. Pu L. Tetrahedron 59 (2003) 9873
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During the review of this paper, Rh-catalyzed enantioselective arylation of trifluoromethyl ketones appeared: Martina, S. L. X.; Jagt, R. B. C.; de Vries, J. G.; Feringa, B. L.; Minnaard, A. J. Chem. Commun. (advanced article).
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