Reaction of Ta(NMe2)5 with O2: Formation of aminoxy and unusual (aminomethyl)amide oxo complexes and theoretical studies of the mechanistic pathways

Journal of the American Chemical Society

Volumn 129, Issue 46, 2007, Pages 14408-14421

  Chen, Shu Jian ^a   Zhang, Xin Hao ^b   Yu, Xianghua ^a   Qiu, He ^a   Yap, Glenn P A ^c   Guzei, Ilia A ^d   Lin, Zhenyang ^b   Wu, Yun Dong ^b   Xue, Zi Ling ^a  

^a UNIVERSITY OF TENNESSEE   (United States)

^b HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^c UNIVERSITY OF DELAWARE   (United States)

^d UNIVERSITY OF WISCONSIN MADISON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; HYDRIDES; LIGANDS; OXIDATION; X RAY CRYSTALLOGRAPHY;

ELEVATED TEMPERATURES; INTERSYSTEM CONVERSION; MECHANISTIC PATHWAYS;

TANTALUM COMPOUNDS;

AMIDE; OXYGEN; PEROXIDE; TANTALUM; AMINE; CHELATING AGENT; ORGANOMETALLIC COMPOUND;

ARTICLE; CRYSTAL STRUCTURE; DENSITY FUNCTIONAL THEORY; TEMPERATURE; X RAY CRYSTALLOGRAPHY; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; THEORETICAL MODEL;

AMIDES; AMINES; CHELATING AGENTS; MODELS, CHEMICAL; MODELS, THEORETICAL; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXYGEN; TANTALUM;

EID: 36448941858     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja075076a     Document Type: Article

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