Carbonyl Insertions into Metal-Nitrogen Bonds of Group 4 Dialkylamido Complexes. X-ray Structure of Cp*(Me2N)2Ti[O(Me2N)C]W(CO)5

Organometallics

Volumn 14, Issue 1, 1995, Pages 131-136

  Galakhov, Mikhail ^a   Martín, Avelino ^a   Mena, Miguel ^a   Palacios, Federico ^a   Yélamos, Carlos ^a   Raithby, Paul R ^b  

^a UNIVERSITY OF ALCALÁ   (Spain)

^b UNIVERSITY OF CAMBRIDGE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001041104     PISSN: 02767333     EISSN: 15206041     Source Type: Journal    
DOI: 10.1021/om00001a022     Document Type: Article

References (16)

1. (a) For a comprehensive review see: Stephan, D. W. Coord. Chem. Rev. 1989, 95, 41. (b) Ferguson, G. S.; Wolczanski, P. T.; Parkanyi, L.; Zonnevylle, M. C. Organometallics 1988, 7, 1967. (c) Anslyn, E. V.; Santarsiero, B. D.; Grubbs, R. H. Organometallics 1988, 7, 2137. (d) Erker, G.; Mena, M.; Hoffmann, U.; Menjon, B. Organometallics 1991, 10, 291, and references cited therein. (e) Beckhaus, R.; Strauss, I.; Wagner, T.; Kiprof, P. Angew. Chem., Int. Ed. Engl. 1993, 32, 264. (f) Petz, W. J. Organomet. Chem. 1993, 456, 85.
2. (a) Metal-Support Interactions in Catalysis, Sintering and Redispersion; Stevenson, S. A., Dumesic, J. A., Baker, R. T., Ruckenstein, E., Eds.; Van Nostrand-Reinholdt: New York, 1987. (b) Strong Metal-Support Interactions; Backer, R. T. K., Tauster, S. J., Dumesic, J. A., Eds.; American Chemical Society: Washington, DC; 1986.
3. Bradley, D. C.; Kasenally, A. S. J. Chem. Soc., Chem. Comm. 1968, 1430.
4. (a) Petz, W.; Schmid, G. J. Organomet. Chem. 1972, 35, 321. (b) Petz, W.; Schmid, G. Angew. Chem., Int. Ed. Engl. 1972, 11, 934. (c) Petz, W. J. Organomet. Chem. 1973, 55, C42. (d) Petz, W. J. Organomet. Chem. 1974, 72, 369. (e) Petz, W.; Jonas, A. J. Organomet. Chem. 1976, 120, 423. (f) Petz, W. J. Organomet. Chem. 1979, 165, 199.
5. Janik, J. Fr.; Duesler, E. N.; Paine, R. T. J. Organomet. Chem. 1987, 323, 149.
6. (a) Martín, A.; Mena, M.; Raithby, P. R.; Serrano, R.; Yélamos, C. J. Organomet. Chem. 1994, 467, 79. (b) Galakhov, M.; Irigoyen, A. M.; Martín, A.; Mena, M.; Monge, M.; Palacios, F.; Yélamos, C., manuscripts in preparation.
7. (a) Nakamoto, K Infrared and Raman Spectra of Inorganic and Coordination Complexes, 4th ed., Wiley: New York, 1986. (b) King, R. B.; Bisnette, M. B. J. Organomet. Chem. 1967, 8, 287. (c) Bradley, D. C.; Gitlitz, M. H. J. Chem. Soc. A, 1969, 980. (d) Bürger, H.; Dämmgen, U. J. Organomet. Chem. 1975, 101, 295.
8. Beckhaus, R.; Strauss, I.; Wagner, T., J. Organomet. Chem. 1994, 464, 155.
9. (a) Gómez Sal, M. P.; Martín, A.; Mena, M.; Royo, P.; Serrano, R. J. Organomet. Chem. 1991, 419, 77. (b) Gómez-Sal, M. P.; Mena, M.; Royo, P.; Serrano, R. J. Organomet. Chem. 1988, 358, 147. (c) Mena, M.; Royo, P.; Serrano, R.; Pellinghelli, M. A.; Tiripicchio, A. Organometallics 1989, 8, 476. (d) Gómez-Sal, M. P.; Mena, M.; Palacios, F.; Royo, P.; Serrano, R.; Martinez-Carreras, S. J. Organomet. Chem. 1989, 375, 59.
10. Feldman, J.; Calabrese, J. C. J. Chem. Soc., Chem. Commun. 1991, 1042.
11. (a) Orpen, A. G.; Brammer, L.; Allen, F. H.; Kennard, O.; Watson, D. G.; Taylor, R. J. Chem. Soc. Dalton Trans. 1989, S1. (b) Dötz, K. H.; Fischer, H.; Hofmann, P.; Kreissl, F. R.; Schubert, U.; Weiss, K. Transition Metal Carbene Complexes; Verlag Chemie: Weinheim, 1983; p 103. (c) Erker, G.; Dorf, U.; Benn, R.; Reinhardt, R. D.; Petersen, J. L. J. Am. Chem. Soc. 1984, 106, 7649. (d) Erker, G.; Dorf, U.; Lecht, R.; Ashby, M. T.; Aulbach, M.; Schlund, R.; Krüger, C.; Mynott, R. Organometallics 1989, 8, 2037.
12. March, J. Advanced Organic Chemistry: Reactions, Mechanisms and Structure, 3rd ed.; John Wiley & Sons: New York, 1985; p 19 and references therein.
13. Martin, G. J.; Gouesnard, J. P.; Dorie, J.; et al., J. Am. Chem. Soc. 1977, 99, 1381.
14. Binsch, G. Top. Stereochem. 1968, 3, 97.
15. Nakamoto, K.; McCarthy, P. J. Spectroscopy and Structure of Metal Chelate Compounds; Wiley: New York, 1968.
16. Sheldrick, G. M. J. Appl. Cryst., manuscript in preparation.