Synthesis and crystal structure of unprecedented phosphine adducts of d1-aryl imido-vanadium(IV) complexes

Inorganic Chemistry

Volumn 42, Issue 3, 2003, Pages 673-675

  Lorber, Christian ^a   Choukroun, Robert ^a   Donnadieu, Bruno ^a  

^a LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

PHOSPHINE DERIVATIVE; VANADIUM DERIVATIVE;

ARTICLE; CHEMICAL REACTION; COMPLEX FORMATION; CRYSTAL STRUCTURE; DERIVATIZATION; DRUG DETERMINATION; MAGNETISM; PHASE TRANSITION; SPECTROSCOPY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0037429239     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic026089m     Document Type: Article

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27. 3 is insoluble in most common organic solvents, except in dichloromethane, where it is, however, not stable very long, with precipitation of insoluble material (possibly following decoordination of one dmpe ligand or resulting from an equilibrium mixture in solution). As a result, interpretation of the EPR spectrum of this complex was not possible.
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